HomeMy WebLinkAbout7.03 Water Quality Report 06.29.10encana ..
~·
June 29, 20 10
Garfield County Building & Planning Department
108 81h Street, Suite 201
Glenwood Springs, CO 8160 I
27 17 County Road 2 15, Sui te I 00
Parachu te, CO 8 1635
P: (9 70)285-27 39
RE : Hunter Mesa Water Treatment Facility Water Quality Data.
Dear Sir or Madam:
Pleas e find the attached data summaiy table and laboratmy analysis report for waler samples
collected from th e Hunter Mesa Water Treatment Facility on May 04, 20 I 0. The data summa1y
table also li s ts several reference standards for comparison with the a nalyt ica l res ults. T hese
s tanda rd s are provided for r e lativ e comparison o nly, as the water is not intended to co mply with
any of the referenced regulatmy s ta ndards. The water will be contained on si te o r u sed s ol e ly for
natu ral gas exploration and production acti vi ti es. A s such, the water wi ll not come in contact
with the gen era l public or with e nvironmental receptors s uch as soil , g round water, or surface
water.
Please do n ot hesitate to contact our Parachute office should you have any questions or
comments.
Sincerely,
EHS F ie ld C oordina tor
Alla chm ent s
Cc: Dav id Gri ss o, Encana Oi l & Gas (USA) In c .
Brenda Lin ster, Enca na Oil & Ga s (USA) In c.
Fil e
RECEIVED
JUL 0 ~ 2010
GARF IELD COUNTY
BU ILD ING & PLANN ING
Facility: Hunter Mesa Water Treatment Plant
Sample Date: May 4, 201 O
Sample Identifier: HUNTERSOUTHPOND-050410
Sample Location: South Pond
•south Pond was dry at time of sampling due to maintance cleaning.
Laboratory Analytical Report Summary
Analytical Regulatory Standards
Test Parameter Units Result Level Reference Number
Chloride
Fluoride
Bromide
Nitrate
Nitrite
Sulfate
Ammonia
pH
Soecific conductance
Dissolved Solids
Arsenic
Barium
Cadmium
Chromium
Coooer
Iron
Lead
Maanesium
Manganese
Selenium
Potassium
Silver
Sodium
Benzene
Toluene
Ethylbenzene
Total X'lene
Methane
Sulfide
Methyl tert-butyl ether (f\!TBE)
TPH-GRO
Alkalinity
Alkalinity, Bicarbonate
Alkalinity, Carbonate
Notes:
mg/I = milligrams per liter
i.igll = micrograms per liter
tJmhos/cm = micromhos per centimeter
NTU = nephelomelric turbidity units
pH = parts of hydrogen
su = standard unit
BDL = below detection limit
Standard Reference Numbers:
mg/I NT
mg/I NT
mg/I NT
ma/I NT
mg/I NT
mg/I NT
mg/I NT
SU NT
µmhos/cm NT
mail NT
mg/I NT
ma/I NT
mail NT
mail NT
mg/I NT
mg/I NT
mg/I NT
mg/I NT
mg/I NT
mg/I NT
mg/I NT
ma/I NT
mg/I NT
ma/I NT
ma/I NT
mg/I NT
mg/I NT
mg/I NT
mg/I NT
µg/I NT
mg/I NT
mg/I NT
mg/I NT
mail NT
250 1,5
4.0 1
none N/A
10.0 1,2,3,4
1.0 1
250 1,5
none N/A
6.5-8.5 1,3,5
none N/A
·--
500 1,5
0.01 2
2.0 2,4
0.005 2,4
0.1 2,3
1 4,5
5.0 3
0.015 4
none N/A
0.05 5
0.05 2,4
none N/A
0.05 2
none N/A
0.005 3
1 4
0.7 4
10 4
none N/A
none N/A
none N/A
none N/A
none N/A
none N/A
none N/A
Standard 1 = Colorado Department of Public Health and Environment Drinking Water Regulations Maximum Contaminant Levels
Standard 2 = Colorado Department of Public Health and Environment Water Quality Control Commission Ground Water Standards • Human Health Standar
Standard 3 = Colorado Department of Public Health and Environment Water Quality Control Commission Ground Water Standards -Agricultural Standards
Standard 4 =U.S. Environmental Protection Agency National Primary Drinking Water Standards
Standard 5 =U.S. Environmental Protection Agency National Secondary Drinking Water Standards
NIA = No applicable standard exists in referenced regulations.
Facility: Hunter Mesa Water Treatment Plant
Sample Date: May 4, 2010
Sample Identifier: HUNTERMIDDLEPDND-050410
Sample Location: Middle Pond
Laboratory Analytical Report Summary
Analytical Regulatory Standards
Test Parameter Units Result Level Reference Number
Chloride
Fluoride
Bromide
Nitrate
Nitrite
Sulfate
Ammonia
pH
Seecific conductance
Dissolved Solids
Arsenic
Barium
Cadmium
Chromium
Conner
Iron
Lead
Maanesium
Manqanese
Selenium
Potassium
Silver
Sodium
Benzene
Toluene
Ethylbenzene
Total Xylene
Methane
Sulfide
Methyl tert-butyl ether (MTBE)
TPH-GRO
Alkalinity
Alkalinit~. Bicarbonate
Alkalinity, Carbonate
Notes:
mg/I = milligrams per lile1
µg/I = micrograms per liter
µmhosfcm = micromhos per centimeter
NTU = nephelomelric turbidity units
pH = parts of hydrogen
su = standard unit
BOL = below detection limit
Standard Reference Numbers:
ma/I 3,770
mall 32.9
mall 103.0
ma/I 0.12
ma/I 0.12
mall 41.3
mg/I 5
SU 7.97
µmhos/cm 18,600
mall 12,400
mall 0.0046
ma/I 35.9
ma/I 0.0003
mall 0.0028
mall 0.0059
mg/I 1.68
ma/I 0.0017
ma/I 10.8
mall 0.352
ma/I 0.0032
ma/I 84.7
mall 0.0008
mall 3,900
ma/I 3.670
mg/I 8.960
mg/I 0.35400
mg/I 5.450
mg/I 0.393
mg/I 0.15
µg/I BDL
mg/I NT
mg/I 2,760
ma/I 2,720
mall 42.4
250 1,5
4.0 3,5
none N/A
10.0 1,2,3,4
1.0 1
250 1,5
none N/A
6.5-8.5 1,3,5
none N/A
500 1,5
0.01 2
2.0 2,4
0.005 2,4
0.1 2,3
1 4,5
5.0 3
0.015 4
none N/A
0.05 5
0.05 2,4
none NA
0.05 2
none N/A
0.005 1
1 1
0.7 1
10 1
none N/A
none N/A
none N/A
none N/A
none N/A
none N/A
none N/A
Standard 1 = Colorado Department of Public Health and Environment Drinking Water Regulations Maximum Contaminant Levels
Standard 2 = Colorado Department of Public Health and Environment Water Quality Control Commission Ground Water Standards • Human Health Standan
Standard 3 "' Colorado Department of Public Health and Environment Water Quality Control Commission Ground Water Standards -Agricultural Standards
Standard 4"' U.S. Environmental Protection Agency National Primary Drinking Water Standards
Standard 5 =U.S. Environmental Protection Agency National Secondary Drinking Water Standards
NIA"' No applicable standard exists in referenced regulations.
Facility: Hunter Mesa Water Treatment Plant
Sample Date: May 4, 2010
Sample Identifier: HUNTERSOUTHPOND-050410
Sample Location: South Pond
·south Pond was dry at time of sampling due to maintance cleaning.
Laboratory Analytical Report Summary
Analytical Regulatory Standards
Test Parameter Units Result Level Reference Number
Chloride
Fluoride
Bromide
Nitrate
Nitrite
Sulfate
Ammonia
pH
Specific conductance
Dissolved Solids
Arsenic
Barium
Cadmium
Chromium
Copper
Iron
Lead
Magnesium
Manganese
Selenium
Potassium
Silver
Sodium
Benzene
Toluene
Ethylbenzene
Total Xylene
Methane
Sulfide
Methyl tert-butyl ether (MTBE)
TPH-GRO
Alkalinity
Alkalinitv, Bicarbonate
Alkalinity, Carbonate
Notes:
mg/I = milligrams per liter
l'Q/I = micrograms per liter
µmhos/cm = micromhos per centimeter
NTU = nephelometric turbidity units
pH = parts of hydrogen
su = standard unit
BDL = below detection limi1
Standard Reference Numbers:
mo/I NT
ma/I NT
mg/I NT
ma/I NT
mo/I NT
ma/I NT
mg/I NT
SU NT
µmhos/cm NT
ma/I NT
mg/I NT
ma/I NT
ma/I NT
ma/I NT
mg/I NT
ma/I NT
ma/I NT
ma/I NT
mg/I NT
ma/I NT
ma/I NT
ma/I NT
mg/I NT
ma/I NT
ma/I NT
ma/I NT
mg/I NT
ma/I NT
mg/I NT
µg/I NT
mg/I NT
ma/I NT
ma/I NT -
ma/I NT
250 1,5
4.0 1
none N/A
10.0 1,2,3,4
1.0 1
250 1,5
none N/A
6.5-8.5 1,3,5
none N/A
500 1,5
O.D1 2
2.0 2,4
0.005 2,4
0.1 2,3
1 4,5
5.0 3
0.015 4
none N/A
0.05 5
0.05 2,4
none N/A
0.05 2
none N/A
0.005 3
1 4
0.7 4
10 4
none N/A
none N/A
none N/A
none N/A
none N/A
none N/A
none N/A
Standard 1 = Colorado Department of Public Health and Environment Drinking Water Regulations Maximum Contaminant Levels
Standard 2 = Colorado Department of Public Health and Envir<mmenl Water Quality Control Commission Ground Water Standards -Human Health Standar
Standard 3 =Colorado Department of Public Health and Environment Water Quality Control Commission Ground Waler Standards -Agricultural Standards
Standard 4: U.S. Environmental Protection Agency National Primary Drinking Water Standards
Standard 5 =U.S. Environmental Protection Agency National Secondary Drinking Water Standards
NIA = No applicable standard exists in referenced regulations.
1111!1 Gulf Coast
gACCUTEST.
I ii h (J I (l I c \
ACCUTEST
LABORATORIES
1956-2006
0
ll 'S A LL IN lH E C fl E Mt s 1 nv
Technical Report for
EN CANA
GARCO Hunter Mesa Water Facility
Accutest Job Number: T52063
Sampling Date: 05/04/10
Report to :
EnCana
2717 Co. Rd. 215
Parachute, CO 81635
e-Hardcopy 2.0
A utomated Report
05/24/10
brett . middleton @e ncana.com; Daniel. Prokop @e ncan ii.. co m
A TIN: Brett Middl eton
Total number of pages in report : 46
\~ ACCo~
(<.9 O.q Q~ +(\
i<i ~
ff ~
u ""
"' :i:
Test result s co ntain ed within thi s data pa ckag e me et the requiremerlls
of th e National Environmental Laboratory Accredita tion Co nference
and/o r state spe ci fic certification programs as appli cab le .
Client Service contact: Sylvia Garza 713 -271 -4700
Paul Canevaro
Laboratory Direc tor
Cer tifi ca ti ons: TX (Tl047042 20-09C -TX) AR (88 -07 56) F L (E87628) KS (E-10366) LA (85695/04004)
OK (9103) UT(713 2714700)
This rep ort s hall not be reprodu ced, except in it s en tirety. without the written approval of Accutes t Laboratories.
Test re sult s relate only to sa mpl es analyzed.
Gulr Coast • 10165 Harwin Drive • Suite 150 • Houston, TX 77036 • tel: 713-27 1-4 700 • fax : 7 13-271 -4770 • http ://www .acc ut cst.com
Accutes t Laboratories is th e sole authorit y for auth orizing edi ts or modi fi ca tions to thi s
document. Unauthori zed modifi ca tion of this report is stri ctly prohib ited .
1!1 1!1 1 of 46
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Sections:
T able of C ontents
-1-
Section 1: Sample Summary ................................................................................................... 3
Section 2: Case Narrative/C onformance Summary .............................................................. 4
Scctio11 3 : S am1>lc l~csults ........................................................................................................ 8
3 .1: T520 63-l : HUNTERNORTHP OND-0504 10 .............................................................. 9
3 .2: T52063-l F: HUNTERNORTHPOND-050410 (DISSOLVED) .................................. 12
3.3: T52063-2 : HUNTERMIDDLEPOND -0504 10 ............................................................. 13
3.4: T52063-2F: HUNTERM IDDLEPOND-050410 (D ISSOLVED) ................................ 16
Sectio11 4: Misc. Forms ............................................................................................................ 17
4.1: Chain of Custody .. . .. .. . .. . .... .. . . . . . .. .. .. .. . . .. . . . . . . .. .. . . . .. . . . .. . . . .. .. .. . .. .. . . .. .. .. . .. . .. .. . . . . . . .. .. . . . . . . .. . .. . . 18
Sectio n 5: GC/MS Vo latil es -QC Data Summaries .............................................................. 21
5.1: Method B l ank Summary .... ... . ...... ....... .... . ... ...... ... .... ........ ...... ........ ...... ........ ..... .. ...... ... . . 22
5.2: Blank Spike Su1n 1nary ................................................................................................... 24
5.3: Matrix Spike/Matrix Spike Duplicate Summary........................................................... 26
S cdion 6 : Metal s Analys is -Q C Dat a S ummaries ................................................................ 2 8
6.1: Prep QC MP 11732: As,Ba,Cd,Ca,C r ,Cu,F e,Pb,Mg,Mn,K,Se,Ag ,Na .. ........ .... ....... .. .. .. 29
Section 7: General Chemistry -QC Data Summaries .......................................................... 34
7.1: Method Blank and Spike Resu lts Summary .................................................................. 35
7.2: B lank Spike D upli cate Resu lts Summary...................................................................... 36
7.3: Dupl icate Res u lts Summary .......................................................................................... 37
7.4: Matrix Spike Results Summary..................................................................................... 38
Section 8: Misc. Forms (Accutest Laboratories Southeast, Inc.) ......................................... 39
8.1: Ch ain of Custody . ..... . . ... .. . ..... ..... . . ... .. . .... . . ... . ... . . .. . .... . . . ..... ..... .. . . . ........ ............ ... .. . ..... .. . . 40
Section 9 : GC Volatiles -QC Data (Accutest Laboratories Southeast, Inc.) ...................... 42
9.1: Method Blank Summary ................................................................................................ 43
9.2: B lank Spike Summary ................................................................................................... 44
9.3: Matrix Spike Summary ............................................................................................. ..... 45
9.4: Dup licate Su 1n1nary ......... ...... .......... ............................................................. ................. 46
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Accutest Laboratories
Sample Summary
E N CAN A
GARCO Hunter Me sa Water Facility
Sample
Number
Collected
Date Time By
T52063-l 05/04/ I 0 I 0 : I 0
T 52063-IF 051041I0 I 0: I 0
T52063-2 05/04/ I 0 I 0:40
T52063-2F 051041I0 I 0:40
Matrix
Received Code Type
05105 110 AQ Water
051051I0 AQ Water Filtered
051051I0 AQ Water
05105110 AQ Water Filtered
Job No:
Client
Sample ID
T52063
HUNTERNORTH POND-050410
HUNTERNORTH POND-0504 10
(DISSOLVED)
HUNTERMIDD LEPOND-050410
HUNTERMIDDLE POND-050410
(DISSOLVED)
I
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L a b o r a l o ,. r c s
SAMPLE DELIVERY GROUP CASE NARRATIVE
Client: ENCANA Job No T 52063
Site: GA RCO Hunter Mesa Water Fac ilit y Report Date 5/22/20 10 11 :27:5 6 A M
4 Sa mp le(s ), we re co llec ted on 05/04 /2 0 10 and were rece ive d at Ac cutes t on 05/05/2010 properly pres erv ed , at 5.1 Deg . C and int act.
These Samp les receive d an Accu tes t jo b nu mb er o fT 52063. A lis ting o f the Labo ratory Samp le ID, C lient Sam ple ID and dates o f
collec tio n are p resented in the Res ult s S umm ary Sec tion of th is report.
Excep t as no ted b elow, all met hod s p ec ifi ed calib ra tions and q ua lity contro l perfonn ance c ri ter ia were met fo r this jo b . Fo r more
info rm at ion, p lease re fe r to QC summary p ages .
Volatiles by GCMS By Method SW846 8260B
j Matrix AQ Batch ID : VX535
• All s am ples were analyze d within the reco mm ended met ho d hold ing time.
• All meth od b lanks for thi s batch mee t me tho d sp ec ific c rite ri a.
Matrix AQ Batch ID: VX536
• All samp les were analyzed wi thi n th e reco mm end ed me thod ho lding ti111 e.
• All meth o d b lanks for this batch mee t meth od s p ec ifi c criteria.
• Sa 111p le(s) T5 1846-IMS, T 5 1846-IMS D were us ed as the Q C sa 111 p les indi cated .
Volatiles by GC By Method RSKSOP -147/175
j Matrix AQ Batch ID : F:GFF21 0
• T 52063: Analys is perfo rmed at Acc ut es t Lab orator c s, O rlando , FL.
Metals By Method SW846 6010B
j Matrix AQ Batch ID: M P I 1732
• All sa mp les we re d iges ted w ithin the reco111mend ed meth o d ho ldin g t im e.
• All sa mpl es were ana lyze d w ithin th e recommend ed meth o d ho ld ing time.
• All metho d bl anks for this b atc h mee t met ho d s pec ific criter ia.
• Sa111p le(s) T 5206 1-IF DUP , T5206 1-I FMS, T5206 1-I FMS D, T 52 06 1-IFS DL we reused as the QC samp les fo r metals .
• RPD (s) for Serial Di lut ion fo r Cadmium , Chro mi um , Po tass iu m are o ut s id e cont ro l !unit s fo r sa mp le MP 11 732-S DI. P ercent
d iffere nce acceptab le du e to low initial sample co nce ntra ti o n (< 50 ti111 es ID L).
Wet Chemis try By Method EPA 120.1
j Matrix AQ Batch ID: GN2283 0
• All sa mp les were ana lyze d w ithi n the reco111m end ed 111e th o d ho lding ti111 e.
• All me thod blanks for th is batc h meet metho d s pecific criteria.
• Sa111p le(s) T5 1989-I DUP were used as the QC samp les fo r S pec ific Co nduc tivity .
Saturday, May 22, 2010 P age 1 of3
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Wet Chemistry By Method BP A 300/SW846 9056
I Matrix AQ Batch ID: GP8860 II
• All samples were distiUed with in the recom mended meth od ho lding time .
• All sa mples were ana lyze d withi n the reco mmen ded me th od ho lding ti me .
• All method b lanks for this batc h meet meth od s pecific criteria.
• S am p le(s) T52 155-2DUP , T52 155-2MS were used as the QC samp les for Chl oride.
Matrix AQ Batch ID: GP8894
• A ll sa mp les were dis till ed withi n the reco mm ended method ho ld ing time.
• All sa mp les were an a lyzed wit hin th e recommended meth od ho ld ing time.
• A LI me th od b lanks for thi s batch mee t method s p ec ific criteri a.
• Samp le(s) T52063 -1 DUP, T52063-I MS we re used a s th e QC samples fo r Bro m ide, F luoride, Sulfa te, Bromide.
• Mat ri x Sp ik e Rccovery(s) fo r Bro mide, Fluoride, S ul fa te are o ut s ide contro l limit s. Probab le cause due to matr ix interfe rence.
Wet Chemistry By Method SM 21 4500 NH3D
I Matrix AQ Batch ID: GP8826
• A ll samp les were dis tilled wi thin the recom me nded me tho d ho ldin g time.
• A ll samp les were analyzed within the rec omm ended met hod holding tim e.
• A LI met hod b lank s fo r this batc h meet method s pec ifi c c rit eria.
• Sample(s) T522 1 I-I DUP, T522 1 I-I MS were used as the QC samp les for Nitrogen , Ammon ia.
• RPD(s) for Dup li cate for Nitrogen, Am mo ni a are outs ide contro l li mits for samp le GP8826-D I.
Wet Chemistry By Method SM 2320B
I Matrix AQ Batch ID : GN22938
• ALI samp les were ana lyzed with in the recommended me th od ho ld ing tim e.
• All method b lank s for this bat ch me et me th od s pec ifi c c riteria.
Wet Chemistry By Method SM 2540C
I Matrix AQ Batch ID: GN22589
• A ll samp les were ana lyzed withi n the recommended meth od ho ld in g time .
• All me th od b lanks for this batc h mee t meth od s p ec ifi c c riter ia.
• Sam pl e(s ) TS 1979-1 DUP were us ed as th e QC s amples for Solid s, T o tal Diss olv ed .
Wet Chemistry By Method SM 4500 C02 D
I Matrix AQ Batch ID: GN22740
• ALI samples were ana lyzed within th e rec o mmended method hold ing ti me.
• All me thod b lanks for thi s batc h meet method spec ific crit eri a.
• Sampl e(s) TS 1898 -1 DUP were used as the QC s amp les fo r Alka linity, Bicarb onate.
Wet Chemistry By Method SM 4500H+B/9040
I Matrix AQ Batch ID : GN22607
• Sampl e(s) T 52063 -ID UP were used a s the QC s amp les for pH .
Sa turday, Ma y 2 2 , 2010 Page 2 o f3
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Wet Chemistry By Method SM 4500S+F
I Mat rix AQ Bat ch ID : GN22666
• All samples were analyzed within th e recomm end ed me th od holdi ng tim e.
• All method blan ks for this batch mee t method s pe cific crit eria.
Wet Chemistry By Method SM 18 2320B
I Matr ix AQ Batch ID : GN22741
• All samples were ana lyze d within th e reco mmend ed method holding tim e.
• All method b lanks for this batc h meet meth od s pe c ifi c c rit eria.
• Sample (s) T52269-IOUP we re used as th e QC samp les for Alkalinity, Carbonate.
Acc utest Laboratories G ulf Coas t (ALGC) certifies th at this repo rt meet s th e project requirement s for analytical da ta produced for th e
samp les as rece ived at ALGC and as s tated on the COC. ALGC certi fies th at th e data mee ts th e Data QualityObjectives for precisio n,
accuracy and compl eteness as spec ifi ed in the ALGC Q ualit y Manua l exce pt as noted above. This re port is to b e used in its en tirety.
ALGC is not respo ns ib le fo r any ass umpt ions of d ata quality if pa rti al d ata packages are used
Saturday, May 22, 2010 Page 3 of3
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1
SAMPLE DELIVERY GROUP CASE NARRATIVE
Client : Accutest Laboratories Gulf Coast, Inc. Job No: T52063
Site: ENCACOP: GARCO Hunter Mesa Water Facility Report Date 5111120 10 12:47:29
2 Sa mples were co ll ected on 05 /04/2 010 a nd were received at Accutes t, SE on 05/06/20 10 properl y preserved , at 2.6 Deg. C a nd
int act. T hese Samples received an Accutestjob number ofT52063. A li sting o f th e Laboratory Sampl e ID , Cl ie nt Sampl e ID and
dates of coll ect ion are presented in the Resu lt s Summary Section of th is report.
Except as noted below, all method speci fi e d cali brati o ns and quality control perfonnance criteria were me t for this job. For more
information, pl ease refer to QC summary pages.
Volatiles by GC By Method RSKSOP-147/175
Matrix: AQ Batch ID: GFF2 I 0
All samples were analyzed w ithin the recommended me thod holdi ng time.
A ll method blank s fo r thi s batch meet method speci fic c riteria.
Sample(s ) F732 15-4DUP, F732 I 5-4MS were used as the QC samples indicated.
Accutest Laboratori es Southeast (ALSE) certifies that thi s report meets the project req uire me nt s fo r analyti cal data produced for th e
sa mples as received at ALSE a nd as stated on the COC. ALSE certifi es th at the data meets the Data Qua lity Objecti ve s fo r precis ion,
accuracy a nd com plete ness as specifi ed in the ALSE Qual ity Manual except as noted above . T hi s report is to be used in its entirety.
ALSE is not respo nsib le fo r any assumptions o f data qua li ty if pa11ial data packages are used
Narrat ive pre pare d by :
Date: May 11 , 20 10
Lovel ie Metzgar, QA As s istant (signa ture on fil e)
Tuesday, May 11 , 2010 Page 1 of I
II
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tll!I Gulf Coast
gACCUTEST.
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0
JT ·s ALL lt4 THE CHEMISTllY
Sample Results
Report of Analysis
Section 3
II
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~ACCUIESt
T52063 I ' ' '
Accutes t Laboratories
R e port of Analysis P age I of I
Client Sample ID: HUNTERNORTHPOND-0504 10
Lab Sample ID : T52063-I Date Sampled: 05/04/10 I
Matrix: AQ-Water Date Received : 05105110
Method: SW846 8260B Percent Solids: n/a
Project: GARCO Hunte r Mesa Water Facility
Fil e ID OF Analyzed By Prep Date Prep Batch Analytical Batch
Run #I X0061066.D 100 05/08/10 JL n/a n/a VX536
Ru n #2
IRuu #I
Purge Volume
5.0 ml
Run #2
Purgeable Aromatics, MTBE
CAS No. Compound Result RL MDL Units Q
7 1-43-2 Benze ne 4 .60 0 .20 0 .05 0 mg/I
10 8-88-3 Toluene 9.62 0 .20 0 .043 mg/I
100-41-4 Eth yl benze ne 0.283 0.20 0.055 mg/I
1330-20-7 Xylene (tota l) 4 .59 0.60 0.17 mg/I
16 34-04-4 Methyl Teri Buty l Ether ND 0.20 0.073 mg/I
CAS No. S urrogate Recovedes Run# I Run# 2 Limits
1868-53-7 Dibromoflu orom ethane 89%
17060-07-0 I , 2-D ichloroethane-D4 87%
2 037-26-5 To lu ene-08 90%
460-00-4 4 -Bromofluorobenzene 92%
ND = Not detected MDL -Me thod Detection Limit
RL = Report in g Lim it
E = Indicat es va lu e exceeds ca li bration range
79-122%
75-12 1%
87-11 9%
80-133%
J = Indicates an estim ated va lue
B = Indi cates a nalyte found in associa ted m etho d blank
N = In d icates presumptive evidence o f a compound
fll!t 9 of 46
;iACCUTEST.
T52063 I
Accut est Lab ora tories
Report of Analysis Page I of I
C lie nt Sample ID: HUNTERNORTHPOND-050410
Lab Sample ID: T52063-I Date Sampled: 05/04 /10
Matrix: AQ-Water Date Receiv e d: 05/05/10
Method: RSKSOP-147/175 Percent Solids: n/a
Project: GARCO Hunter Mesa Water Facility
F il e ID DF A n alyzed By Prep Date Prep Batch Analytica l Batch
Run #I a FF04859.D I 051 I 0/ I 0 AFL n/a n/a F:GFF2 10
Run #2
CAS No. Compound Res ult RL MDL Un its Q
74-82-8 Methane 0 .167 0 .000 50 0 .000 16 mg/I
(a) Analysis performed at Accutes t Laboratories, Orlando, FL .
ND = Not detec ted MDL -Method Detecti on Limit
RL = Repor tin g Limit
E = Indicates va lue exceeds c a libration range
J = Indicates an estim ated va lu e
8 = Indicates analyte fo und in ass oc iated m e th od bl ank
N = Indi cate s presumpti ve evide nce o f a com pound
w :....
I
Accutest Labora tories
Report of A na lysis Page I of I ~ .....
Client Sample IO: HUNTERNORTHPOND-050410
Lab Sample ID : T52063-1
Matrix: AQ-Water
Project: GARCO Hunter Mes a Water Facility
General Chemistry
Analyte Result RL MDL
Alkalinity, Bicarbonate 2090 5.0 0.66
Alkalinity, Carbona te 6.7 5.0 0.66
A lka linity, Total as CaC03 2 100 5.0 I. 7
Bromide 105 2.5 0.50
C hlor ide 4660 500 190
Fluoride 66.1 2.5 1.3
Nitrogen, Ammonia 5.9 0.10 0.0060
Nitrogen, Nitrate 0.12 u 0.50 0.12
Nitrogen, Nitrite 0.12 u 0.50 0 .12
Solids, Total Di sso lved 13300 200 52
Specific Conduct iv ity 20500 1.0
Sulfate 50.4 2.5 0.75
Sulfide 0.15 u 0.20 0. 15
pH 7.55
RL = Reporting Limit
MDL = Method Detection Limit
Date Sampled: 05104 1I 0 I
Date Received: 05105110
Percent Soli ds: n/a
Units DF Analyzed By Method
mg/I 05/13110 M C SM 4 500 C02 D
mg/I 05/1 7/10 M C SMl8 23 20B
mg/I I 05113/1 0 M C SM 23208
mg/I 5 05/1 5/10 19 :02 BF EPA 300/S W846 9 056
mg/I 1000 05/13/10 20:01 BF EPA 300/S W846 9 05 6
mg/I 5 05/15/10 19:02 BF EPA 300/S W 846 9 05 6
mg/I 0511 2/10 15:3S BF S M 21 4SOO NH 3 D
mg/I I OS /OS/I 0 17 : S4 BF EPA 300/S W846 9 0S6
mg/I I OS/OS/I 0 17: S4 BF EPA 300/S W846 9 0 S6
mg/I I 05/0 S/I O BG S M 2S40C
umh os/cm I OS/1 7/10 09:30 MC EPA 120. I
mg/I 5 OS / I Sil 0 19:02 BF EPA 300/S W846 9 0S6
mg/I OS /10/10 10:00 K D SM 4SOOS+ F
SU OS/0 511 0 17:00 C N SM 4 500H+ B/9040
U = In d icates a result < MDL
B = In dicates a res ult > = MDL but < RL
tl.!H!'.I 11 ot 46
;iACCUTEST.
T52063 1 '
Ac c utcst Laboratories
Rep ort of A nalysis Pa ge I of I w
N
C lie n t Sample ID: HUNTERNORTHPOND-0504 10 (DISSOLVED) I Lab Sample ID : T52063-IF Date Sampled: 05104110
Matrix: AQ -Water Fi lt ered Date Received : 05105 110
Percent Solids: n/a
Project: GARCO Hunter Mesa Water Faci lit y
Dissolved Metals Analysis
Analyte R es ult RL MDL Units DF Prep Analyzed By Method Prep Method
Arsen ic 0 .0025 B 0.0050 0. 0020 mg/I I 05 108110 051121I0 NS SW846 60 10B I SW846 3010A 3
Bari um 49.3 1.0 0 .014 mg/I 5 05 /08/10 05116110 NS SW846 60 108 2 SW846 30 JOA 3
Cad mium 0 .00030 u 0 .0040 0.00030 mg /I I 05 /08/10 05 112110 NS SW846 60 10B I SW846 3 0 10A 3
Calcium 213 5.0 0.035 mg /I 05 108110 05112110 NS SW846 6010B I SW846 30 10A 3
Chromium 0 .0032 B 0 .010 0 .0019 mg/I 05108110 05112110 NS SW846 60 10B I SW846 3 0 10A 3
Copper 0.0068 B 0.025 0 .0059 mg /I 05 108110 05112110 NS SW846 60 10B I SW846 3010A 3
Iron 1.90 0.10 0 .01 3 mg/I 05 /08/10 05112110 NS SW846 60 10B I SW846 3010A 3
Lead 0.0017 u 0.0030 0 .0017 mg/I 05 /08/10 05112110 NS SW846 60 I OB I SW8 46 30 JOA 3
Magnes ium 16.0 B 25 0 .039 mg/I 5 05/08/10 051161I0 NS SW846 60108 2 SW846 30JOA 3
Manganese 0.557 0.015 0 .0076 mg/I 05108110 0511 211 0 NS SW846 60 10 B I SW846 3010A 3
Potassium 88.9 5.0 0.053 mg/I 05 /08/10 05112110 NS SW846 60 10 8 I SW846 3010A 3
Se lenium 0.0032 u 0.0050 0.0032 mg/I 05 /08 /10 05112110 NS SW 846 60 108 I SW846 3010A 3
Sil ver 0.00080 u 0.010 0.000 80 mg/I I 051081 10 05/12/10 NS SW846 6010B I SW846 30 10A 3
So dium 4440 250 6.7 mg/I 50 05/0 8/10 051 16/10 NS SW846 6010B 2 SW846 30 10A 3
{I) In strument QC Batch : MA4734
(2) In strument QC Batch : MA4747
(3) Prep QC Batch : MP 117 32
RL = Re porting Limit U = In dicates a r esult < MDL
M DL = Meth od De tection Limit B = In d ica te s a result > = MDL but < RL
fBl!'j 12 of 46
liiiACCUTEST.
T 52 063 I •
Accutest Lab oratories
Report of Analysis Page I o f I w w
C lient Sample ID: HUNTERMIDDLEPOND-050410
Lab Sample ID : T52063-2 Date Sampled: 05104 110 I
Matrix: AQ -Water Date Received : 05/05 /10
Method : SW846 8260B Percent So lids: n/a
Proj ect: GARCO Hunte r Mes a Water Faci lity
File ID OF Analyzed By Prep Date Prep Batch Analytical Batch
Run #I X006 1067.D 50 05/08/10 JL n/a n/a VX536
Run #2 a X006 1027.D 500 05/08/10 JL n/a n/a VX535
Purge Volume
Run #I 5.0 ml
Ru n #2 5.0 ml
Purgeable Aromatics, MTBE
C AS No. Compound Result RL MDL Units Q
71-43-2 Ben zene 3.67 0 .10 0.025 mg/I
108-88-3 Tolu ene 8.96 0 .10 0 .022 mg/I
100-41 -4 Eth y lb enzene 0.354 0.10 0.027 mg/I
1330-20-7 Xylene (total) 5.45 0.30 0.084 mg/I
1634 -04-4 Methyl Teri But y l Eth er ND 0.10 0.036 mg/I
CAS No. S urrogate R ecove ries Run# 1 Run# 2 Limits
1868 -53-7 Dibromofluoromethane 89%
17060 -0 7-0 I ,2-Dich loroeth ane-D4 88%
2037-26-5 Toluene-08 92%
460-00-4 4-Bromoflu oroben zene 95%
(a) Reported for Q C purposes only.
ND = Not detec ted MDL - Meth od Detection Limit
RL = Repor ting Li mit
E = Indi cate s va lue exceeds ca libration ran ge
91%
90%
9 1%
9 1%
79-122%
75-121%
87-1 19 %
80-1 33%
J = Indi ca tes an estimated va lu e
B = In d icates ana lyte fo un d in associated m ethod blank
N = Indicat es presumptive ev ide nce of a compound
fml!i 13 of 46
lliiACCUTEST.
T52063 1
Accut est Laboratories
Report of Analysis Page I o f I w w
Client Sample ID: H UNTERM I DD LE PON D-050410
Lab Sample ID: T52 06 3-2 Date Sampled: 05/04/10 I
Matrix: AQ -Water Date Received: 05105110
Meth od: RSKSOP-1471175 Percent Solids: n/a
Project: GARCO Hunter Mesa Water Facility
File ID DF Analyzed By Prep Date Prep Batch Analytical Batch
Run #I a FF04860.D I 05110110 AFL n/a n/a F:GFF210
Run #2
C AS No. Compou nd Res u lt RL MDL U n its Q
74-82 -8 Methane 0.393 0 .00050 0 .0001 6 mg/I
(a) Analys is p erformed at Accutest Laboratories, Orlando, FL.
ND = Not detected MDL -Method Detection Limit
RL = R epor tin g Limit
E = Indi cates va lue exceeds calibra tion range
J = Indi cates an es tim ated va lue
B = Indi cates analy te found in associated m e th od b lank
N = Indi cates presumpti ve eviden ce of a com po und
flm l!I 14 of 46
l;iACCUTEST.
T52063 1 •
Accutest Lab oratories
Report of Analys is Page I of I w w
Client Sample ID: HUNTERMIDDLEPOND-050410
Lab Sample ID: T52063-2
Matrix: AQ-Water
Project: GARCO Hunter Mesa Water Facility
General C h emistry
Analyte Result RL MDL
Alkalinity, Bicarbonate 2720 5.0 0.66
Alkalinity, Carbonate 42.4 5.0 0.66
Alkalinity, T ota l as CaC03 2760 5.0 1.7
Bromide 103 2 .5 0 .50
C hloride 3770 500 190
F luoride 32.9 2.5 1.3
Nitrogen, Ammonia 5.0 0 .10 0.0060
Nitrogen, Nitrate 0 .12 u 0.50 0. 12
Nitrogen, Nitrite 0.12 u 0.50 0 .12
So lids, Total Di ssolved 12400 200 52
Specific Conductivity 18600 1.0
Su lfate 41.3 2 .5 0.75
Su lfide 0.15 u 0 .20 0 . 15
pH 7.97
RL = R e portin g Limit
MDL = M ethod Detection Lim it
Date Sampled: 05/04/10 I
Date Received: 05/05/10
Percent Solids: n/a
Units DF A n alyzed By Method
mg/I 05 /13/10 MC SM 4500 C02 D
mg/I 05 /17/10 MC SM l 8 2320B
mg/I 05/13/10 MC SM 2320B
mg/I 5 05115110 19:54 BF EPA 300/SW846 9056
mg/I IOOO 05113110 19 :43 BF E PA 300/SW846 9056
mg/I 5 05/15/10 19:54 BF EPA 300/SW846 9056
mg/I I 05/12/10 15: 35 BF SM 2 1 4500 NH3D
mg/I 05 /0 5110 18:46 BF EPA 300/SW84 6 9056
mg/I 05/05/10 18:46 BF EPA 300/SW846 9056
mg/I 05/05/1 0 BG SM 25 40C
umhos/cm 05 /17/10 09:30 MC EPA 120.1
mg/I 5 05/15/10 19:54 BF E PA 300/S W846 9056
mg/I I 0 5/1 0/1 0 10:00 KD SM 45 00S+ F
SU I 0 5/05/1 0 17:00 CN SM 4 500H + B/9040
U = Indi cates a result < MDL
B = Indi cates a r esult > = MDL but < RL
fB l!t 15 of 46
&;iACCUTEST.
T5206 3 I ' ' ' '
Accutest Lab orato ri es
R e port o f An a lysis Page I o f I w
li.
C li en t Sample ID: H UN T E RM ID D L EPON D-0504 10 (DISSO L YEO ) I Lab Sample ID : T 520 63-2F Date Sampled: 05104110
Matrix : A Q -Water F ilter ed Date Received : 05105110
Percent Soli d s : n/a
Project: GARCO Hunter M esa Water Facility
Dissolved Metals Analysis
Analyte Re sul t RL MDL Units DF Prep Analyzed By Method Prep Method
Ar senic 0.0046 B 0 .0050 0 .0 02 0 m g/I 05/0 8/10 05112110 NS SW846 60 I OB I SW846 30 10A 3
Ba rium 35.9 1.0 0 .0 14 m g/I s 05/0 8/10 05116110 NS SW846 60 10B 2 SW846 30 10A 3
Cadmium 0 .00030 u 0 .0 040 0 .00030 m g/I 05/0 8/ I 0 051 121 10 NS SW846 60 10B I S\V846 30 10A 3
Calcium 144 5.0 0 .0 35 m g/I 0 5/0 8/10 05 /12/10 NS SW84 6 60 10 B I SW846 30 10A 3
C hro mium 0 .002 8 B 0 .010 0 .0019 m g/I 05/0 8/10 05/12/10 NS SW846 60 10 B I SW846 3010A 3
Cop per 0 .0 059 u 0 .025 0.0 059 mg/I 05/0 8/10 05/12/10 NS SW846 601 0B I SW846 30 10A 3
Iron 1.68 0 .10 0 .0 13 mg /I 05/0 8/10 05/12/10 NS SW846 60 10B I SW846 30 10A 3
Lead 0 .00 17 u 0 .0030 0 .001 7 m g /I I 05/08/ I 0 05112/ I 0 NS SW846 60 I OB I SW846 30 10A 3
M agnesiu m 10.8 B 25 0.039 mg/I 5 05/0 8/ I 0 051 161I0 NS SW846 60 I OB 2 SW846 3010A 3
Manganese 0 .352 0.0 15 0.007 6 mg/I I 05/08/ I 0 05112 / I 0 NS SW846 60 108 I SW846 30 10A 3
Potass ium 84 .7 5.0 0 .053 mg/I I 05/0 8/ I 0 051 12/ I 0 NS SW846 601 08 I SW846 30 10A 3
Se lenium 0 .0032 u 0 .0050 0 .00 32 mg/I I 0 5/08/ I 0 OS/ 12/ I 0 NS SW8 46 60 108 I SW846 30 10A 3
Silver 0.0008 0 u 0.0 10 0 .000 80 mg/I I 0 5/08/ I 0 051 12/ I 0 NS SW846 60 108 I SW846 30 10A 3
Sodium 390 0 25 0 6.7 mg/I 50 0 5/0 8/ I 0 05 1161 I0 NS SW846 60 108 2 SW846 301 0A 3
(I) In strument QC Batch : MA4 734
(2) Instrument QC Ba tch : MA4747
(3) Pr ep QC Batc h : MP I 17 32
RL = Re portin g Limit U = Indi ca tes a r esult < MD L
MDL = Me thod Detecti o n Limit B = In dicates a result > = M D L b ut < RL
fl!!) 16 of 46
ljiACCUTEST.
T52063 I '
Bl!'J Gulf Coast
liACCUTEST.
l abor lr • c;
0
IT 'S AL L 1'4 TH E C H !M t s tnv
Misc. Forms
Custody Documents and Other Forms
Includes the following where app li cable:
• C hain of C u stody
Section 4
II
fm l!i 17 of 46
l:;'i ACCUTEST.
T52063 I • ' ' '
,(111!1
riACCUTEST.
Lab or at ories
flmW.tfi!l Cllon l I Reporting lnlormallon
~y NllM
E """'r. OiHr-,n_<.{J1CJ! )//IL.
SlrHIMOfUt '
J717 Cr .i.1 s su.,;+e...100
Pro)lttf.111111•:
CHAIN OF CUSTODY
1016' 1-Wwia Or, Stt ISO HOYl.lon. TIC l10l6
TEL 7U·2ll°"100 FAX: 711·271-4110
'fl"4'W.ACCUlH ltoOI
Prolecl I nformation t •.
G•\f~Cb i-k"-W-M.e..5.cdJ..lcd-cr t=n.w l ; t-., .......
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Profltd~ E--r111t PrGJtc:UI l!ltrltlM«th
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0 20.tRVSH
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1......--0rdatCtMIOl l
R ecues t e d An•IY•ll MalrbcCocles
"-~·OrinldrgWaler
CW ·<bundWQ1 ww.w ..
SW ·S&HfKll Wt":er
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'WP·Yt\I•
f'B-AtldBlar.k
El-Equ~B&ri
RB-Rln MllllM
TB·TrlpBlalik
LAB USE ONLY
T52 063: C hain of C ustody
Pagel of 3
I
111!1 18 of 46
l;'iACCU1EST.
T52063 I'
SAMPLE INSPECTION FORM
Accutest Job Number: l '5d:::Y..o3 Client: U)CAAfA-Date/Time Received: 5/5,/to O'it5
#of Coole rs Recelved: ______ Th ermometer .11: ___ 1~[<_-_1 _____ Temperature Adju stment Factor: ·r 0. L/ °C
.CoolerTemps:. ~l: 5 ,)"C #2: #3 : #4: ____ #5,: ____ 116: #7: #8 :
. Mottt;d of Doli'<n" \.2) __ UP_S_ Acc utest Courter Greyhound Deliv_e_ry ___ Othe_r ___ ------
Airbill Numbers: ____________________________________________ _
COOLER INFORMATION
§Cus tody seal mJ ~s lng or not Int act
Tempera ture c r1tcr1a not m e t
Wet Ice received ln coole r
CiiAJN OF C USTODY
ChaJ n of Custody not rec eived
Sample D/T unclear or missing
Analyses unclear or missing
COC not properly exe cuted
S ummary of Discrepancies:
SAMPLE INFORMATION
Sample conla1ncr:1 rccclvcd broken
voe vtals have hcadspace
Sample labels mtsstng or Wegtble
ID on COC docs not match Jabel(s)
D/T on COC does not ma tch labet(s)
Sample/Bottles rcvd but no analysts on COC
Sam pl e li sted on COC, but not received
Bottles mlsstng for requested analysts
lnsuftlctcnt vo lume for analys is
Sample receive d Improperly preserved
INF ORMATION 4t'fD S AMPLE LABELING VERIFIED BY:
... . .. CORRECTIVE ACTIONS
Client Representative Notified:
By Accutest RepFesentatlve:'------------------'--------
Client Ins truetlons:
TRIP BLANIC INFORMATION
n1p Blank on COC but not recelilctl
n1p Blank receive d but not on COC
Tup Blank not Intact
Rec eived Wa te r T'rtp Blank
Received Sou TB
Number of Encores?
Number of 6035 ldts?
Number of lab -fUt cred metals? _____ _
Via: Phone Emal\
·--·------·----·-----·-------------------------------------------------------------·--.................. .:. ................................................................... -........................................................................... :---·-------·
·------·--------·------------------------------------·····----------------·-··-------·---..................................................................................................................................................................................... . ...
T52 063: C hain of C ustody
Page 2 of3
I
f!Dl!'.t 19 of 46
s;iACCUTEST.
T52063 1
JOB#: --z{ d,0 (p "?>
CLIENT: CNCAtVI\
COOLER# SA~PLE ID FIE LD ID
I 1 HutJf~H PoN D _ ()'>041 c
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~ 1-\,..rl/n:> M\l)Ol£fl;."'\)-Q<i7\t{IG
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---~
~
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SAMPLE RECEIPT LOG
OATEfTIME RECE IVED : ~5/t v CJ9f":l
I NITIALS:
-'----~~~~~~~~~~~~~~~~
DA T E MATRIX VOL BOTTLE# L OCATION PRES ERV P H
S/'-//10 tJ /Oo?MI \-d. "?:>? !-.!)_ 2 3 4 <2 >12 /C./O 5 8 7 8 ·'
'dl)DM/ 3 1 2 3~ <2 >12 5 6 . 7 . 8
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5 8 7 <8D
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"'<'7 4aml to -11 Vil-~.J 2 3 4 <2 >12 -5 8 7 6
ICI:C<n l I -::t sp ,y 2 3 4 <2 >12 1040 5 8 7 8
d.Q°)(Y,I 3 1 2 3 ~ <2 >12 5 6 7
4 <;;?'"',~ 1 2 ,3(8) ~ ~n'A..c >12 fl 5 8
~I ,;-?J!'l r; ( ...Gi l.Y. 2 3 4 <2 >12 5 6 7 8
""'? ~ ..., <;r lfOMI fo -11 \)Cf-~ 2 3 4 <2 >12
5 8 7 6 . " . <2 >~ 5 6 . 7 8
1 2 3 4 ___...--;;2
5 8 7 _.....-
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---------1 2 3 4 <2 >12
' 5 8 . 7 8
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5 B 7 8
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<2 >12 5 8 7 8
--------
1 2 3 4 <2 >12
' 5 8 7 8
1 2 3 4 <2 >12 5 6 7 8
1 2 3 .4 <2 '>12 5 8 7 8
1 2 3 ·4 <2 >12
5 8 7· 8
1 2 3 .. ·4 <2 >12 5 a . 7 8
1 2 3 . . ~ <2 >12
" "
I
PRESERVATIVES: 1: Nooe 2: HCL 3: HN03 4: H2S04 5: NAOH 6: DI 7: MeOH 8: Olhar
LOCATION: 1: Walk-In #1 jWalers) 2: Wal~-ln #2 !Sol ls) VR: Volatile F~dg e M: Me\als SUB: Subcoo lracl EF: Encore Freeze r
T52 063: C hain of C ustody
Page 3of3
llJl!i 20 of 46
l;iACCUTEST.
T52063 1 '
fll!t Gulf Coast
l;iACCUTEST.
L il b (J f t ("I I c '>
0
IT 'S All !ti TH E C tt E MI S l RY
GC/MS Volatiles
QC Data Summaries
Includes the following where a pplicable:
• Method Blank S ummaries
• Bl a nk Spike S ummaries
• Matrix Spik e a nd Dupli cat e S ummar ies
Section 5
&11!1 21 of 46
l';iACCU'"f EST.
T520 63 I
Method Blank Summary
Job Number: T52063
Account: ENCACOP E NCANA
Project: G ARCO Hunter Mesa Water Facility
Sample
VX 535-MB
Fi le ID OF
X0061023.0 I
Analyzed By
05/0 7/1 0 JL
The QC reported h ere applies to the fo llowi n g sa mples:
T52063-2
Prep Date
n/a
Prep Batch
n/a
Page I of I
A n a l)1tical Batch
VX 535
Method: SW 846 8260B
CAS No. Compound R es ult RL MDL Units Q
CAS No. S urrogate Recoveries
1868-53 -7 Oibromoflu orometh anc
17060-07-0 l ,2-0ic hloroethan e-04
2037 -26-5 Toluene-08
460-00-4 4 -Bromofluorobenzenc
Limits
92% 79-122%
91% 75-12 1%
90% 87-11 9%
9 1% 80-133%
t.111!1 22 of 46
;iACCUTEST.
T52063 ' •
Method Blank Summary
Job Number: T52063
Account: ENCACOP ENCANA
Project: GARCO Hunte r M esa Water Facility
Sample
VX536-MB
File ID OF
X 0061055.D 1
Analyzed By
05108110 JL
Prep Date
n/a
The QC reported here applies to the followin g samples :
T52063-l , T52063-2
CAS No. Compound Result RL MDL Units
71-4 3-2 Be nzene ND 2 .0 0.50 ug/I
100-41-4 Ethy lbcn zene ND 2.0 0.55 ug/I
1634-04-4 M e th y l Teri Buty l Eth e r ND 2.0 0 .73 ug/l
108-88-3 Toluene ND 2.0 0.43 ug/l
13 30-20-7 Xylene (total) ND 6 .0 I. 7 ug/l
CAS No. Surrogate Recoveries Limits
1868-53-7 Dibromo fluo rome tha n c 90% 79-122%
17060-07-0 l ,2-Dichloroetha ne-D4 9 0% 75-12 1%
2037-26-5 Tolu cne-D 8 92% 87-1 19%
460-00-4 4-Bro mo fluo robenzene 90% 80-133%
Prep Batch
n/a
Page 1 o f 1
Ana lytical Batch
VX536
Method : SW846 82608
Q
t!J l!i 23 of 46
;iACCUTEST.
T 52 063 I
Blank Spike Summary
Job Number: T52063
Account: ENCACOP ENCANA
Project: GARCO Hunter Mesa Water Facility
Sample
VX535-BS
File ID DF
X0061021.0 I
Analyzed By
05/07110 JL
The QC reported here applies to the following samples:
T52063-2
Spike BSP BSP
Prep Da te
n/a
CAS No. Compound ug/I ug/I % Limits
CAS No. Surrogate RecoYeries BSP Limits
1868-53-7 Oibromofluoromethane 91% 79-122%
17060-07-0 I ,2-0ichloroet ha ne-04 89% 75-12 1%
2037-26-5 Tol uenc-08 92% 87 -119%
460-00-4 4-Bromofluorobenzene 88% 80 -133%
Page I of I
Prep Batch Analytical Batch
n/a VX535
Method: SW846 82608
lll!i 24 of 46
gACCUTEST.
T52063 I
Bl a nk Spike Summ ary
Job Number: T52063
Accou nt: ENCA COP EN CANA
Project: GARCO Hunter Mesa Water Facili ty
Sample
VX536-BS
Fil e ID DF
X0061053.D I
A n a lyzed By
05/08/10 JL
T h e QC reported h ere applies to t h e fo ll owing sam p les:
T52063-l , T52063-2
S p ike BSP BSP
CAS No. Compou nd ug/I u g/I %
71-43-2 Benzene 25 22.6 90
100-41 -4 Et hyl be nzene 25 24.2 97
1634-04-4 M ethyl T eri Buty l Eth er 25 20.2 8 1
108-88-3 Toluene 25 23.7 95
1330-20-7 Xylene (total) 75 72.4 97
CAS No. S u rrogate R ecoveries BSP Li mi ts
1868-53 -7 D ibromofluoro1n et ha ne 90% 79-122%
17060-07-0 1, 2-Dichl oroethane-04 90% 75-12 1%
2037-26-5 Tolu ene-08 94% 87-11 9%
460-00 -4 4 -Bro mo fl uorob enze ne 9 1% 80-133%
Prep Dat e
n/a
L imits
76-118
75-112
65-113
77-11 4
75-111
Prep Batch
n/a
Page I of I
An a lytical Ba tch
VX536
01
N
"'
Meth o d : SW846 8260B
fll l!i 25 of 46
l;iACCUTEST.
T52063 I " ., I t I
Matrix Spike/Matrix Spike Duplicate Summary
Job N umber : T52063
Account: ENCACOP ENCANA
Project: GARCO Hunter Mesa Water Faci lity
Sample
T52063-2MS
T52063-2MSD
T52063-2 a
File lD OF
X006 I 028. D 500
X006 1029.D 500
X006 1027.D 500
Analyzed By
05108110 JL
05108110 JL
05108110 JL
T he Q C r eported here applies to the followin g sa mples:
T52063-2
CAS No. Compound
CAS No. S urrogate Recove ries
1868-53-7 Dibromofluoromcth ane
17060-07-0 l ,2-Dichloroethane-D4
2037-26-5 Toluene-08
460-00-4 4-Bromofluorobcnze n e
(a) Reported fo r QC purposes o nl y .
T52063-2
u g/I Q
MS
90%
9 1%
93%
89%
S pike
u g/I
MSD
9 1%
89%
92%
89%
Prep Date
n/a
n/a
n /a
MS
ug/I
MS
%
T52063-2
9 1%
90%
9 1%
91 %
Page I of I
Prep Batch Analytical Batch
n/a VX535
n/a VX535
n/a VX5 35
Meth od: SW846 82608
MSD
ug/I
Limits
79-122%
75-1 2 1%
87-1 19%
80-133%
MSD
% RPO
Limits
Rec/RPO
l!ll!'i 26 of 46
gACCU IESt
T 520 63 I · '
Matrix Sp ike/Matrix Spike Duplicate Summary
Job Number : T52063
Account: ENCACOPENCANA
Project: GARCO Hunter Mesa Water Facility
Sample
T51846-1MS
T51846-1MSD
T51846-l
File ID OF
X006 1061.D 1
X006 I 062 . D 1
X006 I 060. D 1
Analyzed By
05/0811 0 JL
05/08110 JL
05 /08 /10 JL
The QC reported here applies to the fo ll owing samples:
T52063-l , T52063-2
T51846-1 Spike
CAS No. Compound ug/I Q ug/I
71-43-2 Benzene ND 25
100-41 -4 Ethyl benzene ND 25
1634-04-4 Me thyl Teri Butyl Ether ND 25
108-88-3 To lu ene ND 25
1330-20-7 Xylene (total) ND 75
CAS No. S u rrogate Recoveries MS MSD
1868-53-7 Dibromofluoro1netha ne 90% 90%
17060-07-0 1, 2-Dich loroethane-04 90% 90%
2037-26-5 To lu cne-D8 94% 93%
460-00-4 4-Bromofluorobenzene 92% 89%
Prep Date
n/a
n/a
n /a
MS MS
ug/I %
23.7 95
25.2 101
21.1 84
24.9 100
75.5 101
T51846-I
91%
88%
91%
90%
Page 1 of 1
Prep Batch Analytical Batch
n/a VX536
n/a VX536
n/a VX536
Method: SW846 82608
MSD MSD Limits
u g/I O/o RPO Rec/RPO
22.8 91 4 76-118/16
24.6 98 2 75 -112/12
21.7 87 3 65-11 3113
24.4 98 2 77-1 14/12
74 .2 99 2 75-1 11/12
Limits
79-122%
75 -12 1%
87-119%
80 -133%
flll!'j 27 of 46
liiACCUTEST.
T 52063 I '
mJ l!I Gulf Coast
;iACCUTEST.
l a b () t I ('I ,-C '
0
1r ·s Al l ltl THE C H El~J STRY
Metals Analysis
QC Data Summaries
Includes the following where applicab le:
• Me th od Blank Summ aries
• Matrix Spike and Duplicate Summaries
• Blank Spike and Lab Co ntrol Sa mple Summ aries
• Seria l Di luti on Summ ar ies
Section 6
an 28 of 46
l;iACCU I ESt
T 52063 1
BLANK RESUL TS SU MMARY
Part 2 - Meth od Bl a nk s
Login Nu mber : T52 06 3
Accoun t : EN CACOP -EN CANA
Project : GA RCO Hu n ter Mesa Wa ter f acilit y
QC Batch ID : MP ll 732 Metho ds: SW846
Matrix Type: AQUEOUS Un i ts: u g/l
Prep Dale : 05/08/10
'Me ta l
MB
RL IDL MDL raw fin a l
Al um i nu m 200 16 17
An timony 5 .0 2 .3 3
Arsen ic 5.0 1.8 2 1.1 <5 .0
Barium 200 .14 2 .7 0 .19 <2 00
Beryl liu m 5.0 .11 .2
Boron 100 1.1 2 . l
Cadmium 4.0 .25 .3 0.20 <4.0
Ca lc i um 5000 5 .4 35 -0.93 <5 000
Chromium 10 1.1 1. 9 -0 .57 <10
Cobalt 50 .5 . 8
Copper 25 .58 5 .9 0 .57 <2 5
Iron 100 13 13 -14 <100
Lead 3 .0 1. 6 1 .7 0 .11 <3 .0
Mag nesium 50 00 6 .7 7 .8 -0.9 7 <50 0 0
Manganese 15 .2 7 .6 -0.010 <15
Molybd e num 10 .96 1. 3
Nic kel 40 .95 3 .2
Potassi um 5000 53 53 31. 9 <5 00 0
Selen ium 5 .0 3.2 3 .2 1. 8 <5 .0
Silver 10 .85 .8 0.55 <lO
Sod i u m 50 00 130 130 121 <5 000
Stron tiu m 20 . l7 .4
Thall i um 10 3 .2 2.6
Ti n 2 0 1. 8 2 .9
Ti tan i um 20 . 3 .3
Va n adi um 50 . 6 .6
Zin c 20 . 49 4. I
Associated samp les MP11732 : T52063-l F, T52063-2f
Re s u lts < IDL are shown as zero for calcu lation pu rposes
(.) Out s ide of QC l imits
(a n r ) An al yle no t requ ested
Page 1
60 l0B
?'> _..
:....
I
1!11!'.i 29 of 46
... ACCUTESt
T520 63 I •
MATRIX SPIKE AND DUPLICATE RESULTS SUMMARY
Logi n Nu mb er : T52063
Account: EN CACOP -ENCANA
Project : GA RCO Hun ter Mesa Water Facility
QC Ba tch ID: MP11732 Methods : SW846
Matri x Type : AQUEOUS Un its: ug/1
Pr ep Date: 05/08/10
T520 61-1F QC T52061-1F Spi kelot
Meta l Original DUP RPO Limits Origina l MS MPnl4
Alumi num
An timon y
Arsen ic 0 .0 0.0 NC 0-20 0 .0 414 400
Barium 136 137 0.7 0-20 136 579 400
Beryllium
Boron
Cadmi um 0.69 0 .66 4.4 0-2 0 0.69 41 1 400
Calci um 123000 124000 0.8 0 -20 123000 180000 50000
Chromium 9 .8 9 .1 7 .4 0 -20 9.8 429 400
Cobalt
Copper 63.5 64 . 8 2 .0 0-20 63 .5 4 91 400
Iron 0 .0 0 .0 NC 0-20 0 .0 52300 50000
Lead 0 .0 0.0 NC 0-20 0.0 411 400
Magn esium 51300 51000 2 .0 0-20 5 1300 104000 50000
Mangan ese 269 272 1.1 0-20 ?h'l 696 400
Molybdenu m
Ni c kel a n r
Potas si um 5550 5620 1. 3 0 -2 0 5550 59700 50000
Sel e n i um 0 .0 0.0 NC 0-20 0.0 417 40 0
Silver 0 .0 0.0 NC 0 -20 0.0 429 400
Sod i um 139000 141 000 1.4 0-2 0 139000 19700 0 50000
Strontium
Thall i u m
Tin
Titanium
Vanadium
Zi nc
Associated samples MP11732 : T52063 -l F, T5206 3-2F
Re s u lts < IDL are s hown as zero for calculation p u r poses
(*I Outside o f QC l i mi ts
(NI Matrix Spike Rec . outside o f QC limits
(anr) Analyte not requested
Page 1
6010B
05/08/1 0
% Rec
103.5
110. 8
102.6
114. 0
104. 8
106. 9
104.6
102 .8
108.0
106.8
108 .3
1 04. 3
107 .3
116 .0
QC
Limits
80 -12 0
80-120
80-120
80-120
80-120
80-120
80-120
80 -12 0
80 -120
80-120
80-120
80 -120
80 -120
80-120
!"> ....
iv
I
B l!i 30 of 46
l;iAccun=sT.
T52063 I
MA TRIX SPIKE AND DUPLI CAT E RE SUL TS SUMMAR Y
Login Number : T52063
Ac count : ENCACOP -
Proj ect: GARCO Hunter Mesa
QC Batch ID: MPll 732
Mat r i x Type : AQUEO US
Pre p Date : 0 5/08/10
T52061-1F Spike lot MSD
Metal Origi nal MSD MP TW4 \ Rec RP O
Aluminum
An t imon y
Arsenic 0.0 410 400 102 .5 1.0
Ba r i um 1 36 571 40 0 108 .8 1. 4
Be ryl l i u m
Bo ron
Cadmi um 0 .69 405 400 101. l 1. 5
Calci um 123000 177000 5000 0 108 .0 1. 7
Chrom ium 9 .8 4 25 400 103 .8 0 .9
Cobalt
Co pper 63.5 485 400 10 5 .4 1.2
I r o n 0.0 51 700 5 0000 103 .4 1. 2
Lead 0 .0 405 400 101 .3 1. 5
Magn esi um 51300 102000 50000 104 .0 1. 9
Ma nga nese 269 687 40 0 104.5 1. 3
Molybdenum
Nickel a n r
Potassium 5550 588 00 50000 106 .5 1. 5
Seleniu m 0.0 4 11 400 102 . 8 1. 4
Silver 0.0 419 400 104 .8 2 .4
Sodi um 1390 00 1940 00 50000 110 .0 1.5
Str o n ti um
Thalliu m
Tin
T i ta n i u m
Vanadiu m
Zi nc
Associated samples MPll732 : T52063 -l r, T52063-2P
Resul ts < IDL are shown as ze ro f or calcu lation p u rposes
(') Outsid e o f QC limits
(N) Matrix Spi ke Rec . o u tside of QC l imits
(anr ) Ana lyte not requ ested
Page 2
EN CANA
Wa ter Facility
Methods : SW846
Un its: ug/l
QC
Limi t
20
20
20
2 0
2 0
20
20
20
2 0
2 0
20
20
20
20
6010B
?> ......
;,..,
I
fm l!J 31 of 46
liiACCU I ESt
T52063 1 '
SPI KE BLANK AND LAB CONTROL SA MP LE SUMMARY
Login Nu mbe r: T52063
Account: ENCACOP -
Project: GARCO Hunter Mesa
QC Batch ID: MPll 732
Matri x Type: AQUEOUS
Prep Da te: 05/08/10
BSP Spike lot QC
Meta l Res u l t MPTW4 \ Rec Limits
Al u mi nu m
Antimony
l\C"senic 411 400 102.8 80-120
Barium 443 400 110 .8 80-120
Be rylli um
Boron
Cadmi um 417 400 104 .3 80-120
Calci um 524 00 50000 104 .8 80-120
Chromium 424 400 106.0 80-12 0
Cobalt
Copper 426 400 106 .5 80-120
Iron 52900 50000 105 .8 80-12 0
Lead 415 400 103.8 80 -12 0
Magnesium 51800 50000 103 .6 80 -120
Manganese 425 400 106.3 80-120
Molybdenu m
Nickel a n r
Potassium 50600 50000 1 01.2 80-120
Selen i um 416 40 0 104 .0 80 -120
Silver 42 0 40 0 105.0 80-1 20
Sodium 5140 0 500 00 102.8 80-120
Stron ti um
Thalliu m
Ti n
Titanium
Vanadium
Zi nc
Associated samples MP1 1 732 : T52063 -1F, T52063-2F
Res u l ts < IDL are shown as zero f or cal c u lation purposes
(') Outside oC QC l imits
(anr ) Analyte not r equested
Page l
ENCANA
Water Facility
Me thods : SW846
Un i ts : u g/1
6010B
~ .....
w a
fll!t 32 of 46
gACCUTEST.
T52063 I ••
SERIAL DILUTION RESULT S SUMMARY
Logi n Nu mber: T52063
Account: EN CACOP -ENCANA
Proj ect: GARCO ll unter Mesa Wa te r Facili ty
QC Batch ID: MPll 732
Matr ix Type : AQUEOUS
Prep Date: 05/08/10
T520 61 -1 F QC
Meta l Original SOL 1 : 5 \DI F Limi t s
Aluminu m
Antimo ny
Arsenic 0 .00 0.00 NC 0-10
Bariu m 136 137 1.4 0-10
Beryll ium
Boron
Ca dmi um 0.690 0.00 100.0(a) 0-10
Calci um 1230 00 119000 3 .5 0 -1 0
Chromium 9 .84 6.30 36.0 (a) 0 -10
Cobalt
Copp e r 63 .5 65.4 3.0 0-10
I ron 0 .00 0 .00 NC 0-10
Lead 0.00 0.00 NC 0 -1 0
Magnesiu m 51300 51300 2.7 0 -10
Ma nganese 269 27 4 1. 7 0-10
Mol ybde nu m
Nicke l a n r
Potassiu m 5550 4910 1 1. 6*(b) 0-10
Selen ium 0.00 0.00 NC 0-10
Silver 0.00 0.00 NC 0-1 0
Sodium 139000 133000 3.9 0 -10
Stron t ium
Thall i um
Ti n
Titani um
Vanadi um
Zi nc
Assoc i a ted samples MP11 732 : T52063-1F, T52063-2F
Resu lts < IDL are shown as zero f or calculation pu rposes
(') Outside o f QC limits
(a n r ) Analyte not requested
Methods: SW846
Units: ug/1
6010B
(a) Percent difference acceptab le du e to low initia l sample concentration (< 5 0 times IDL ).
(b ) Seri al di lution indicates possible matrix i n ter fe re nce .
Page 1
!"
~
:i:..
I
f!l l!i 33 of 46
gACCUTEST.
T52063 I •
flll!I Gulf Coast
liACCUTEST.
l (I b (J I t (\I C'
0
IT'S All ltl THE CHEIOSTnv
General Chemistry
QC Data Summaries
Includes the following where applicab le:
• Me th od Blank and Blank Spike Summaries
• Duplicate Summaries
• Matri x Spike Summ aries
Section 7
I
f!Dl!i 34 of 46
liiACCUTEST.
T52063 I • • • ' ' •
METHOD
Project :
Analyte Batch ID
Al k ali n ity, Bicarbonate
Alkalinity, Carbonate
Alkalinity, To t a l as CaC03
Br omid e
GN22740
GN2274 1
GN22938
GP889 4/GN2285 4
Chloride
Fluoride
Nitrogen, Ammonia
Nitrogen, Nitrate
Nitrogen, Ni trite
So l ids, Total Dissolved
Speci f ic Co n d u ctivity
Su lfate
Sulf ide
Associated Samples:
Batch GN2258 9: T52063-l,
Batch GN22666 : T52063-l ,
Batch GN22740 : T52063-l,
Ba t c h GN2274 1: T52063-l ,
Ba t ch GN22830: T52063-l ,
Ba t ch GN22938 : T52063-1 ,
Batch GP8826 : T52 0 63-l ,
Batch GP8860 : T52063-l ,
Batch GP8890 : T52063-l ,
Batch GP8894 : T52 0 63-l ,
(.) Out side o f QC l imits
GP 8 860 /GN2279 7
GP8894/G N22 854
GP8826/G N22729
GP8890/G N22849
GP8890/G N22849
GN22589
GN22830
GP889 4 /G N22 854
GN22666
T52063-2
T52063-2
T52063-2
T5 2 0 63-2
T5 2 063-2
T52063-2
T52 0 63-2
T52063-2
T52 0 63-2
T52063-2
BLANK AND SPIKE RES ULTS SUMM ARY
GENE RA L CHEMISTRY
Login Number: T52063
Accoun t : ENCACOP -ENCA NA
GllRCO Hun ter Mesa Wa t er Fa c i l ity
MB
RL Result Unit s
5 .0 2.0 mg/1
5 .0 0 .0 mg/l
5 .0 2 .0 mg /l
0 .50 0.23 mg/l
0 .50 0.0 mg /l
0.50 0.0 mg/l
0.10 0 .0 10 mg /l
0.50 0.0 mg/l
0.50 0 .0 mg/l
10 0 .0 mg/l
1 .0 <1. 0 u mhos/cm
0 .50 0.0 mg /l
0 .20 0 .0 mg /l
Page 1
Spike BSP
Amo unt Res u lt
2500 2380
10 10 .2
10 10 .1
10 10 .5
5.0 5 .0
10 10 .1
10 10 .8
50 0 5 10
10 10 .0
160 0 1 540
BSP QC
\Recov Li mits
9 5 .2 80-12 0 %
1 0 2 .0 90-11 0 %
101. 0 90-110 %
105 .0 90-11 0 %
100 .0 81-121%
101. 0 90-110\
10 8.0 90-110 % :"I 102 .0 -% ~
100.0 9 0-110\ I
9 6 .2 80-12 0 %
f.1 1!1 35 of 46
l;iACCUTEST.
T52063 1
Analyte Batch ID
Sulf i de GN22666
Associ a ted Samples:
Ba t c h GN22666 : T52063-l , T52063 -2
(') Outsid e of QC l imits
BLANK SPI KE DUPLICATE RE SULTS SUMMARY
GENERA L CHEM ISTRY
Logi n Nu mb er : T52063
Accoun t : ENCAC OP -EN CANA
Proj e ct : GA RCO Hunter Mesa Wate r Fa c i lity
Uni t s
mg/l
Spike
Amount
1600
Page 1
BSD
Result
1540
RPO
0 .0
QC
Limit
II
S l!i 36 ot 46
lrijACCU I EST.
T52063 1 '
Analyte
Alka lin ity , Bicarb onate
Alkalin i t y, Ca rbo nate
Br omide
Chlorid e
Fl uorid e
Nitrogen , Ammo n ia
Nitrogen, Nitrate
Nitroge n, Nitrite
Solid s , Total Di ssolved
Specif ic Con d uctiv ity
Su l fa t e
pH
Assoc iated Samp les :
Batch GN22589: T52 063 -1 ,
Ba tch GN22607: T52 063-l ,
Batch GN22740: T52063-1 ,
Batch GN22741: T52063-1,
Batc h GN22830: T52063-l ,
Ba tch GP8826: T52063-1 ,
Batc h GP8860: T52063-1 ,
Batc h GP8890: T52063-1 ,
Batch GP8894: T52063-l ,
(*) Outside of QC limits
DUPLICATE RESUL TS SUMMAR Y
GENERAL CJIEMISTRY
Login Numb e r : T52063
Account: ENCACOP -ENCANA
Project: GARCO Hun ter Mesa Water Fa c i lity
QC Origin al
Ba tch ID Sample Unit s Resu lt
GN22740 T518 98-l mg/1 312
GN22741 T52269-1 mg/l 5 .1
GP8894/G N2285 4 T52063-l mg/l 1 05
GP8860/G N2279 7 T52 1 55-2 mg/l 40 .7
GP8894/G N2285 4 T52063-1 mg/l 66 .1
GP8826/G N22729 T52211 -1 mg/l 0.0 30
GP8890/G N22849 T52063-l mg/l 0 .12 u
GP8890/G N22849 T52063-l mg/l 0 .12 u
GN22589 T51979-l mg/1 413
GN22830 T51989-l umhos/cm 1590
GP889 4 /G N22 854 T52 063-l mg/1 50.4
GN22607 T52063-1 S U 7 . 55
T52 0 63-2
T52063-2
T52063 -2
T52063-2
T52063-2
T52 063 -2
T520 63 -2
T52063 -2
T52 063 -2
Page 1
DUP
Resul t
3 12
5.2
10 5
35 .0
6 6 .1
0.020
o.o
0.0
410
1590
50.0
7 .56
RP D
0 .0
0 .8
0 .0
1 5 .1
0 .0
40 .0
0.0
0 .0
0 .7
0 .1
0.8
0 .1
QC
Limits
0 -20\
0-20\
0 -20 \
0 -2 0 \
0-20\
0-20 \
0-20 \
0-20 \
0-15 \
0-20\
0-20\
0-6.8 \ I
&11 1!1 37 of 46
QACCUTEST.
T52063 I •
Analyte
Bromide
Ch loride
Fluor i de
Nitroge n , Ammonia
Nitrogen, Ni trate
Nitrogen, Nitrite
Sulfate
Associated samples:
Batch GP8826 : T52063-l,
Batch GP88 60: T52063-l,
Batch GP889 0 : T52063 -l ,
Batch GP8894 : T52063-1,
( *) Outside of QC limits
MATRIX SP IKE RESULTS SUMMAR Y
GENE RAL Cll EMISTRY
Login Nu mber: T52063
Account : ENCACOP -ENCAN A
Project: GARCO Hun ter Mesa Water Fac i l ity
QC Origin al
Batch ID Sample Unit s Result
GP8894/GN22854 T52063-l mg/l 105
GP8860/GN22797 T52155-2 mg/l 40.7
GP8894/GN2285 4 T52063-l mg/1 66 . 1
GP8826/GN22729 T52211-l mg/l 0 .030
GP8890/GN22849 T52063-l mg/l 0 . 12 u
GP8890/GN22849 T5 2063-l mg/l 0 .12 u
GP8894/GN22854 T52063-l mg/l 50.4
T52063-2
T52063-2
T52063-2
T52 06 3-2
(N ) Matrix Spike Rec. o u tside o f QC limits
Page 1
Spi ke MS
Amo un t Result
100 139
200 247
100 1 89
5 .0 4.9
10 1 0 .5
10 22 .0
100 124
QC
%Rec Limits
34.0N 80-120\
10 3 .2 80 -1 20%
1 22 .9 N 80-1 20\
98.0 66-131%
105.0 80 -120\
220 .0N 80-120\
73 .6N 80-120\
....,
:i:i.
I
tB l!t 38 of 46
lgACCUTEST.
T52063
fl'H!I Gu lf Coast
CiACCUTEST.
l ,l h 0 I ( r C \
0
IT 'S ALL IN THE CHfM J STRV
Misc. Forms
Custody Documents and Other For ms
(Accutest Laboratories Southeast, Inc.)
Includes the following where applicable:
• C ha in of Custody
Section 8
I
flll!i 39 of 46
CiACCUTEST.
T 52063 1 •
SU BC ONTRACT CO C
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r(O·IKT••,llrot l~llt01dt1C0<1ttol l
IOlliS Harwi n, Suite I SO -Housto n, TX 77 036 -713 -271-4700 fax: 713-27 1-4770 --~
Ac:cwtn lOw .. •• .t.cn.ltll.lo.., ~I Ob3
I Client lnform1tlon I I Subcontracl Informa tion Reouesled Anafv••• Matrix Codes
Co~yNtint S1.1kon1,..._, Uibortl<Hr
Accutest Gulf Coast ACCUTEST FLORIDA OW•°""""lrloW•~.,
ProjeCICont.ct Email l tbort tOl')'Contul Emtll OW·O'Nl"CIWI~
Svlvla Garza svlvla a@accutest.c:om Samole Recelvlno ww .wu1 ...... i.1
AddltSI Addrtn SW·SVl'KcWr_.,
10165 Harwin Or su;1e 150 so ....
City S11t.t ... City St.alt '"' 0
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Houston TX 77036 "' ot.(><
Phoo1 No . Phone No. 1' UO ·l!Quod w 10l•Olrit1$0lij 713-271-471)() .,
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Coltec~on Number of oreserved botlles c a: .. ...
Accutest Sample Nu mber § i e I ~ l £ ,_
'" i b c; 0 LAB USE ONLY
Dal• ,_ M•ll111 boft!H . lE z
152063·1 514/2010 GW 3 x x
n2oo3·2 51412010 GW 3 x x
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c::=J ~ 01y EMERGENCY 0 Fu1e 01t1 P1chge SAWPLE NOT PltUtftvtD
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c=J 1 Dl)'~MfRCifNC Y Comtn41rCl ll "'A •• RllliftS Only WATCH HOlO TIMEIJ
c=JOthtr Commutl1I •e• • Rt1ul11 & S11nd1rd QC
Rear time ana lytica l ~val/a ble via Lab/ink
~ I 5AMPIJ: CVS ODY MUS T UMfHJf08ElOWfACH ll~f SAMPLES CHANGf POSst.SSION, INCLUOlN ''"
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T52 063: C hain of C ustody
Page 1of2
Accutest Laboratories Southeast, Inc.
I
sn 40of46
Q ACCUTEST.
1 5 2063 I '0
ACCUTEST LABORATOIUES SAMPLE RECEIPT CONFIRMATION
ACCUTEST'S JOll NUMBER: ~s 2-Q b '3 CLIENT: d t ~C:. . PROJECT: ~ <;; f,., 0 b 3
1. I o'f1""" DATUl'IM.E RECEIVED: 0 5-o Q • 0 {MMIDU/YY 24:00} NUMBER OF COOLERS RECEIVED:. _ _.__ __
ME1110D OF DELIVERY: ~ UPS ACCUTEST COURIER GREYHOUND DELIVERY OTHER
Al.Rlll LLNUMBERS:: ___ ....:._ ___________________________________ _
COOLER INFORMATION
C USTODY SEAL NOT PRESENT OR NOT INTACT
Cl!AlN OF CUSTODY NOT R,ECEIVED (COC)
ANALYSIS REQUESTED IS UNCLEAR OR M ISSING
SAMPLE DATES OR TIMES UNCLEAR OR M ISSCNG
TEMPERATURE CRITERIA NOT MET
WET I CE PRESENT
TIUP BLANK INFORMATION
TRJJ' B_LANK PROVIDED
TRir BLANK NOT PROVIDED
TRIP BLANK NOT ON COC
TRIP BLANK INTACT
TRJP B LAN!{ NOT INTAC T
RECEIVED WATER TRIP llLANK
RECEIVED SOIL TRIP BLANK
MISC. INFORMATION
NUMDER OF ENCORES?
NUMDER OF 5035 FJELD KITS ?
NUMllER OR LAB FILTERED METALS?
TEMPERATURE IN FORJl1ATION
OBSERVED TEMPS: J · /.--§IR THERM ID CORR. FACTOR .f 0· t
CORRECTED TEMPS: 1-b
SAMPLE INFORMATION
SAMPLE L ABELS PRESENT ON ALL BOTTLES
INCORRECT NUMBER OF C ONTAINERS USED
SAMPLE RECEIVED IMPROPERLY PRESERVED
INSUF~"I CIENTVOLUllIB FOR ANALYSIS
DATEsrfl.MES ON COC DO NOT M ATCH SAMPLE LABEL
ID 'S ON COC DO NOT MATCH LABEL
voe VIALS HA VE HEAD SP A CE (MACRO Jl UllBLES)
BOTTLES RECElVED BUT ANALYSI S NOT R.EQUF:STED
NO BOTTLES RECEIVED FOR ANALYSIS REQUESTED
UN CLEAR FILTERING OR COMPOSI TING INSTRUCTIONS
SAMPLE CONTAINER(S) RECEIVED BROKEN
'lo SOLIDS JAR NOT RECEI VED
5035 FIELD lCTT FROZEN WJTIUN 48 HOilll'S
RESIDUAL CHLORINE PRESENT
jA PPI CABLE TO EPA 600 SERIES OR 1'0RTJI CAROLINA ORGANICSf
SUMMARY OF COMMENTS'--------------------------------------
H:CHNI C IAN SI GNATURE/lJAl'~-~ 05= 0 6-t D llE\llEWEH S I GNATUREroA rn.~,tj~~~\..:.<;...,lc....&!Lj/:..i.1~()'-----------
NF 10/09 RECE IPT CONFIRMATION 100609 (2).xls
T52063: Chain of Custody
Page 2of2
Ell!I 41 of 46
l;iACCUTEST.
T52063 1 '
lflH!I Gulf Coast
gACCUTEST.
l a t> t) I l I t ,
0
IT 'S AL L 111 TH E C H E MI S T RY
GC Volatiles
QC Data Summaries
(Accutest Laboratories Southeast, Inc.)
Includes the following where appl icab le:
• M e th od Blank Summar ies
• Blank Spike Summaries
• Matrix S pike a nd Dupli cate Summaries
Section 9
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fm l!I 42 of 46
r!iACCUTEST.
T 52063 I •
Method Bla n k Summary
Job Number: T52063
Account:
Project :
ALGC Accut est Laboratories Gulf Coast, In c.
ENCACOP: GARCO Hunter Mesa Water Fac ilit y
Sample
GFF210-MB
File ID DF
FF04854.D
Analy zed By
05/10110 WV
The QC reported h ere applies to the fo ll owing samples:
T 52063-l , T52 063-2
Prep Date
n/a
CAS No. Compound Result RL MDL Un its
74-82-8 Meth ane ND 0 .5 0 0.16 u g/I
Page 1 of 1
P r ep Batch Analytical Batch
n/a GFF2 10
Meth od: RS KSO P-14 7 /175
Q
~ .... :....
I
flll!'i 43 of 46
l;';iACCUTEST.
T 52063 1 '
Blank Spike Summary
Job Number: T52063
Account:
Project:
ALGC Accutest Laboratories Gulf Coast, In c.
ENCACOP: GARCO Hunter Mesa Water Fac ility
Sample
GFF2 10-BS
File ID DF
FF04855.D I
Analyzed By
05110110 WV
The QC reported here applies to the following samples:
T 52 063-l , T52063-2
Spike BSP BSP
Prep Date
n/a
CAS No. Compound ug/l ug/l % Limits
74-82 -8 Methane 108 120 111 54-149
Page I of I
Prep Batch Analytical Batch
n/a GFF2 10
Method: RSKSO P-147/175
I
fll!.t 44 of 46
l;iACCU I ESt
T52063 I • b .... I , I
l
Matrix Spike Summary
Job Number: T52063
Account: ALGC Accutest Laboratories Gulf Coast, In c.
Project: ENCACOP : GARCO Hunter Mesa Water Facility
Sample File ID DF Analyzed By
F732 15-4MS FF04858 .D I 05/10/10 WV
F732 15-4 FF04857.D I 05 /10/10 WV
The QC repor ted here applies to the fo ll owing samples:
TS2063-1 , T52063-2
CAS No. Compound
74-82-8 Methane
F73215-4
ug/I Q
235
Spike
ug/I
108
Prep Date
n/a
n/a
MS
ug/l
344
MS
%
IOI
Page I of I
Prep Batch Analytical Batch
n/a GFF2 10
n/a GFF2 10
Method: RSKSOP-147/17 5
Limits
54-149
<O w :...
tlll!'.I 45 of46
(iACCU IESt
T52063 I \ ~ n ~ 1 r 1
Duplicate S ummary
Job N um ber: T5 20 63
Acco u nt: AL GC Acc utest La b orato ri es Gu lf Coast, Inc.
Proj ect : EN CACOP: G ARCO Hunte r M esa W ater Fac ility
Sample F ile ID DF A n alyzed By
F732 l 5-4D U P FF04 856.D 1 0 5/1 0/1 0 W V
F 732 15-4 F F04857.D I 05/1 0/10 WV
T he Q C r eported h er e ap1>li es t o the fo ll ow ing samples :
T5 2 0 63-l , T 52063-2
F 73 2 15-4 DU P
CAS No . C o mpound u g/I Q ug/I
74 -82-8 Meth ane 235 20 0
Page 1 o f 1
Prep Da te Prep Bat ch Ana lyt ical Bat c h
n/a n/a GFF2 10
n/a n/a GFF2 10
Meth o d : RS KSO P-14 711 7 5
Q R P D Li mits
16 24
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;iACCUI ESt
T52063 I •