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Home My WebLink About5.6 ACZ Report-Final 2015.10.02ACZ Laboratories, Inc. 2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493 Report to: Robert Donnelly Pinnacle Water Inc. 1107 Hendrick Dr Carbondale, CO 81623 Project ID: ACZ Project ID: L26281 Robert Donnelly: Bill to: Robert Donnelly Pinnacle Water Inc. 1107 Hendrick Dr Carbondale, CO 81623 Analytical Report October 02, 2015 Enclosed are the analytical results for sample(s) submitted to ACZ Laboratories, Inc. (ACZ) on August 26, 2015. This project has been assigned to ACZ's project number, L26281. Please reference this number in all future inquiries. All analyses were performed according to ACZ's Quality Assurance Plan. The enclosed results relate only to the samples received under L26281. Each section of this report has been reviewed and approved by the appropriate Laboratory Supervisor, or a qualified substitute. Except as noted, the test results for the methods and parameters listed on ACZ's current NELAC certificate letter (#ACZ) meet all requirements of NELAC. This report shall be used or copied only in its entirety. ACZ is not responsible for the consequences arising from the use of a partial report. All samples and sub -samples associated with this project will be disposed of after November 01, 2015. If the samples are determined to be hazardous, additional charges apply for disposal (typically $11 /sample). If you would like the samples to be held longer than ACZ's stated policy or to be returned, please contact your Project Manager or Customer Service Representative for further details and associated costs. ACZ retains analytical raw data reports for ten years. If you have any questions or other needs, please contact your Project Manager. &imp, ja,,,4 Max Janicek has reviewed and approved this report. is ACC°. ck. e L26281-1510021536 Page 1 of 19 ACZ Laboratories, Inc. 2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493 Pinnacle Water Inc. Project ID: ACZ Project ID: L26281 Case Narrative October 02, 2015 Sample Receipt ACZ Laboratories, Inc. (ACZ) received 1 ground water sample from Pinnacle Water Inc. on August 26, 2015. The sample was received in good condition. Upon receipt, the sample custodian removed the sample from the cooler, inspected the contents, and logged the sample into ACZ's computerized Laboratory Information Management System (LIMS). The sample was assigned ACZ LIMS project number L26281. The custodian verified the sample information entered into the computer against the chain of custody (COC) forms and sample bottle labels. Holding Times Any analyses not performed within EPA recommended holding times have been qualified with an "H" flag. Sample Analysis This sample was analyzed for inorganic, radiochemistry parameters. The individual methods are referenced on both the ACZ invoice and the analytical reports. The extended qualifier reports may contain footnotes qualifying specific elements due to QC failures. In addition the following has been noted with this specific project: The Total Dissolved Solids results for L26281-01 have been qualified with the N1 flag on the extended qualifier report. The chemist noted that the humidity level inside the desiccator was exceeding 30% the morning of 8/31/15, but was measured as being back in range before the sample was removed. L+36 Page 2 of 19 ADZ Laboratories, Inc. 2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493 Pinnacle Water Inc. Project ID: Sample ID: SUMA Inorganic Analytical Results ACZ Sample ID: Date Sampled: Date Received: Sample Matrix: L26281-01 08/25/15 14:20 08/26/15 Ground Water Inorganic Prep Parameter EPA Method Dilution Result Qual XQ Units MDL PQL Total Recoverable Digestion Total Recoverable Digestion Metals Analysis M200.2 ICP -MS M200.2 ICP Date Analyst 09/15/15 20:14 scp 09/04/15 10:34 aeb Parameter EPA Method Dilution Result Qual XQ Units MDL PQL Date Analyst Arsenic, total recoverable Cadmium, total recoverable Calcium, dissolved Copper, total recoverable Iron, total recoverable Lead, total recoverable Magnesium, dissolved Manganese, total recoverable Sodium, dissolved Uranium, total recoverable Zinc, total recoverable M200.8 ICP -MS M200.8 ICP -MS M200.7 ICP M200.7 ICP M200.7 ICP M200.8 ICP -MS M200.7 ICP M200.7 ICP M200.7 ICP M200.8 ICP -MS M200.7 ICP 1 1 0.0003 96.7 B U U 0.14 0.0004 B 14.4 1 5.8 1 0.0039 1 U U mg/L mg/L 0.0002 0.001 09/16/15 20:46 mfm 0.0001 0.0005 09/16/15 20:46 mfm mg/L 0.1 0.5 mg/L 0.01 0.05 mg/L mg/L mg/L mg/L mg/L mg/L mg/L 09/11/15 19:38 aeb 09/09/15 15:39 jjc 0.02 0.05 09/09/15 15:39 0.0001 0.0005 09/16/15 20:46 0.2 1 09/11/15 19:38 0.005 0.03 09/09/15 15:39 jjc mfm aeb jjc 0.2 1 09/11/15 19:38 aeb 0.0001 0.0005 09/16/15 20:46 mfm 0.01 0.05 09/09/15 15:39 jjc REPIN.02.06.05.01 * Please refer to Qualifier Reports for details. L26281-1510021536 Page 3 of 19 ADZ Laboratories, Inc. 2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493 Pinnacle Water Inc. Project ID: Sample ID: SUMA Inorganic Analytical Results ACZ Sample ID: Date Sampled: Date Received: Sample Matrix: L26281-01 08/25/15 14:20 08/26/15 Ground Water Wet Chemistry Parameter EPA Method Dilution Result Qual XQ Units MDL PQL Date Analyst Alkalinity as CaCO3 Bicarbonate as CaCO3 Carbonate as CaCO3 Hydroxide as CaCO3 Total Alkalinity Chloride Conductivity @25C Corrosivity (calc.) Fluoride Hardness as CaCO3 (dissolved) Lab Filtration (0.45um filter) Lab Filtration (0.45um) & Acidification Nitrate/Nitrite as N pH (lab) pH pH measured at Residue, Filterable (TDS) @180C Sodium Adsorption Ratio in Water Sulfate SM2320B - Titration 1 SM4500C1-E SM2510B SM 2330 - CaCO3 SI SM4500F-C SM2340B - Calculation SOPWC050 1 M200.7/200.8/3005A 1 M353.2 - H2SO4 preserved 1 SM4500H+ B SM2540C USGS - 11738-78 D516-02/-07 - Turbidimetric 178 178 6.7 592 0.9 0.15 301 mg/L U mg/L U mg/L mg/L * mg/L umhos/cm * SI Unit B mg/L mg/L 2 20 08/29/15 0:00 tms 2 20 08/29/15 0:00 2 20 08/29/15 0:00 2 20 08/29/15 0:00 0.5 2 09/11/15 14:35 1 10 08/29/15 10:31 10/02/15 0:00 0.05 0.3 09/08/15 14:50 0.8 4 10/02/15 0:00 0.20 mg/L 0.02 0.1 8.1 20.0 386 0.15 H units 0.1 0.1 C 0.1 0.1 mg/L 10 20 5 137 mg/L 5 25 tms tms tms mss2 tms calc enb calc 08/27/15 16:10 sck 09/08/15 12:20 aeb 09/10/15 22:27 pjb 08/29/15 0:00 08/29/15 0:00 08/28/15 10:07 tms tms sck 10/02/15 0:00 calc 09/11/15 10:58 mss2 REPIN.02.06.05.01 * Please refer to Qualifier Reports for details. L26281-1510021536 Page 4 of 19 Method References ADZ Laboratories, Inc. 2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493 Inorganic Reference Report Header Explanations Batch Found Limit Lower MDL PCN/SCN PQL QC Rec RPD Upper Sample A distinct set of samples analyzed at a specific time Value of the QC Type of interest Upper limit for RPD, in %. Lower Recovery Limit, in % (except for LCSS, mg/Kg) Method Detection Limit. Same as Minimum Reporting Limit unless omitted or equal to the PQL (see comment #5). Allows for instrument and annual fluctuations. A number assigned to reagents/standards to trace to the manufacturer's certificate of analysis Practical Quantitation Limit. Synonymous with the EPA term "minimum level". True Value of the Control Sample or the amount added to the Spike Recovered amount of the true value or spike added, in % (except for LCSS, mg/Kg) Relative Percent Difference, calculation used for Duplicate QC Types Upper Recovery Limit, in % (except for LCSS, mg/Kg) Value of the Sample of interest QC Sample Types AS ASD CCB CCV DUP ICB ICV ICSAB LCSS LCSSD LCSW Analytical Spike (Post Digestion) Analytical Spike (Post Digestion) Duplicate Continuing Calibration Blank Continuing Calibration Verification standard Sample Duplicate Initial Calibration Blank Initial Calibration Verification standard Inter -element Correction Standard - A plus B solutions Laboratory Control Sample - Soil Laboratory Control Sample - Soil Duplicate Laboratory Control Sample - Water LCSWD LFB LFM LFMD LRB MS MSD PBS PBW PQV SDL Laboratory Control Sample - Water Duplicate Laboratory Fortified Blank Laboratory Fortified Matrix Laboratory Fortified Matrix Duplicate Laboratory Reagent Blank Matrix Spike Matrix Spike Duplicate Prep Blank - Soil Prep Blank - Water Practical Quantitation Verification standard Serial Dilution QC Sample Type Explanations Blanks Control Samples Duplicates Spikes/Fortified Matrix Standard Verifies that there is no or minimal contamination in the prep method or calibration procedure. Verifies the accuracy of the method, including the prep procedure. Verifies the precision of the instrument and/or method. Determines sample matrix interferences, if any. Verifies the validity of the calibration. ACZ Qualifiers (Qual) B H L U Analyte concentration detected at a value between MDL and PQL. The associated value is an estimated quantity. Analysis exceeded method hold time. pH is a field test with an immediate hold time. Target analyte response was below the laboratory defined negative threshold. The material was analyzed for, but was not detected above the level of the associated value. The associated value is either the sample quantitation limit or the sample detection limit. (1) (2) (3) (4) (5) Comments (1) (2) (3) (4) (5) EPA 600/4-83-020. Methods for Chemical Analysis of Water and Wastes, March 1983. EPA 600/R-93-100. Methods for the Determination of Inorganic Substances in Environmental Samples, August 1993. EPA 600/R-94-111. Methods for the Determination of Metals in Environmental Samples - Supplement I, May 1994. EPA SW -846. Test Methods for Evaluating Solid Waste. Standard Methods for the Examination of Water and Wastewater. QC results calculated from raw data. Results may vary slightly if the rounded values are used in the calculations. Soil, Sludge, and Plant matrices for Inorganic analyses are reported on a dry weight basis. Animal matrices for Inorganic analyses are reported on an "as received" basis. An asterisk in the "XQ" column indicates there is an extended qualifier and/or certification qualifier associated with the result. If the MDL equals the PQL or the MDL column is omitted, the PQL is the reporting limit. For a complete list of ACZ's Extended Qualifiers, please click: http://www.acz.com/public/extquallist.pdf REP001.03.15.02 L26281-1510021536 Page 5 of 19 ACZ Laboratories, Inc. 2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493 Pinnacle Water Inc. Inorganic QC Summary ACZ Project ID: L26281 Alkalinity as CaCO3 SM2320B - Titration ACZ ID Type Analyzed PCN/SCN QC Sample Found Units Rec Lower Upper RPD Limit Qual WG389508 WG389508PBW1 PBW 08/29/15 10:01 U mg/L WG389508LCSW3 LCSW 08/29/15 10:18 WC150825-2 820.0001 787 mg/L 96 90 110 L26341-01DUP DUP 08/29/1511:58 114 113 mg/L WG389508LCSW6 LCSW 08/29/15 13:55 WC150825-2 820.0001 805 mg/L 98 90 110 WG389508PBW2 PBW 08/29/15 14:03 U mg/L -20 20 WG389508LCSW9 LCSW 08/29/15 17:27 WC150825-2 820.0001 807 mg/L 98 90 110 WG389508PBW3 PBW 08/29/15 17:35 U mg/L -20 20 WG389508LCSW12 LCSW 08/29/15 20:32 WC150825-2 820.0001 797 mg/L 97 90 110 WG389508PBW4 PBW 08/29/15 20:38 20.6 mg/L -20 20 WG389508LCSW15 LCSW 08/29/1523:37 WC150825-2 820.0001 799 mg/L 97 90 110 -20 20 Arsenic, total recoverable M200.8 ICP -MS 1 20 ACZ ID Type Analyzed PCN/SCN QC Sample Found Units Rec Lower Upper RPD Limit Qual WG390565 WG3905651CV ICV 09/16/15 20:33 MS150902-7 .05 .05427 mg/L 109 90 110 WG3905651CB ICB 09/16/15 20:36 U mg/L -0.0006 0.0006 WG390469LRB LRB 09/16/15 20:40 U mg/L -0.00044 0.00044 WG390469LFB LFB 09/16/15 20:43 MS150827-2 .0501 .05091 mg/L 102 85 115 L26396-12LFM LFM 09/16/15 21:01 MS150827-2 .0501 .0012 .05351 mg/L 104 70 130 L26396-12LFMD LFMD 09/16/15 21:04 MS150827-2 .0501 .0012 .05269 mg/L 103 70 130 2 20 Cadmium, total recoverable M200.8 ICP -MS ACZ ID Type Analyzed PCN/SCN I QC Sample Found Units Rec Lower Upper RPD Limit Qual WG390565 WG3905651CV ICV 09/16/15 20:33 MS150902-7 .05 .05276 mg/L 106 90 110 WG3905651CB ICB 09/16/15 20:36 U mg/L -0.0003 0.0003 WG390469LRB LRB 09/16/15 20:40 U mg/L -0.00022 0.00022 WG390469LFB LFB 09/16/15 20:43 MS150827-2 .05005 .05021 mg/L 100 85 115 L26396-12LFM LFM 09/16/15 21:01 MS150827-2 .05005 U .04854 mg/L 97 70 130 L26396-12LFMD LFMD 09/16/15 21:04 MS150827-2 .05005 U .04887 1/19/1- 98 70 130 1 20 Calcium, dissolved M200.7 ICP ACZ ID Type Analyzed PCN/SCN QC Sample Found Units Rec Lower Upper RPD Limit Qual WG390235 WG3902351CV ICV 09/11/15 19:17 11150811-1 100 100.01 mg/L 100 95 105 WG3902351CB ICB 09/11/15 19:23 .12 mg/L -0.3 0.3 WG390235LFB LFB 09/11/15 19:35 11150901-3 68.01261 70.24 mg/L 103 85 115 L26371-01AS AS 09/11/15 19:48 11150901-3 68.01261 2 72.71 mg/L 104 85 115 L26371-01ASD ASD 09/11/15 19:51 11150901-3 68.01261 2 71.68 mg/L 102 85 115 1 20 L26281-1510021536 Page 6 of 19 ACZ Laboratories, Inc. 2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493 Pinnacle Water Inc. Inorganic QC Summary ACZ Project ID: L26281 Chloride SM4500CI-E ACZ ID Type Analyzed PCN/SCN QC Sample Found Units Rec Lower Upper RPD Limit Qual WG390247 WG3902471CB ICB 09/11/15 14:24 U mg/L -1.5 1.5 WG3902471CV ICV 09/11/15 14:24 W1150701-4 55.055 59.12 mg/L 107 90 110 WG390247LFB1 LFB 09/11/15 14:35 W1150826-7 29.97 31.84 mg/L 106 90 110 WG390247LFB2 LFB 09/11/15 14:39 W1150826-7 29.97 31.65 mg/L 106 90 110 L26249-01DUP DUP 09/11/15 15:02 1380 1420 mg/L L26249-02AS AS 09/11/15 15:02 50XCL 30 1430 1413 mg/L -57 90 110 3 20 M3 Conductivity @25C SM2510B ACZ ID Type Analyzed PCN/SCN QC Sample Found Units Rec Lower Upper RPD Limit Qual WG389508 WG389508LCSW2 LCSW 08/29/15 10:06 PCN48117 L26341-01DUP DUP 08/29/15 11:58 WG389508LCSW5 LCSW 08/29/15 13:42 PCN48117 WG389508LCSW8 LCSW 08/29/15 17:14 PCN48117 WG389508LCSW11 LCSW 08/29/15 20:19 PCN48117 WG389508LCSW14 LCSW 08/29/15 23:25 PCN48117 1409 1470 umhos/cm 104 90 110 226 225 umhos/cm 1409 1430 umhos/cm 101 90 110 1409 1420 umhos/cm 101 90 110 1409 1400 umhos/cm 99 90 110 1409 1390 umhos/cm 99 90 110 0 20 Copper, total recoverable M200.7 ICP ACZ ID Type Analyzed PCN/SCN QC Sample Found Units Rec Lower Upper RPD Limit Qual WG390035 WG3900351CV ICV 09/09/15 15:14 11150811-1 WG3900351CB ICB 09/09/15 15:20 WG389852LRB LRB 09/09/15 15:33 WG389852LFB LFB 09/09/15 15:36 11150901-3 L26281-01 LFM LFM 09/09/15 15:42 11150901-3 L26281-01 LFMD LFMD 09/09/15 15:45 11150901-3 2 1.965 mg/L 98 95 105 U mg/L -0.03 0.03 U mg/L -0.022 0.022 .499 .485 mg/L 97 85 115 .499 U .499 mg/L 100 70 130 .499 U .494 mg/L 99 70 130 1 20 Fluoride SM4500F-C ACZ ID Type Analyzed PCN/SCN QC Sample Found Units Rec Lower Upper RPD Limit Qual WG389930 WG3899301CV ICV 09/08/15 11:35 WC150904-4 WG3899301CB ICB 09/08/15 11:40 WG389930LFB1 LFB 09/08/15 11:47 WC150626-7 L25473-03AS AS 09/08/15 13:57 WC150626-7 L25473-03DUP DUP 09/08/15 14:03 WG389930LFB2 LFB 09/08/15 14:54 WC150626-7 2 1.904 mg/L 95 95 105 .051 mg/L -0.15 0.15 5 4.797 mg/L 96 90 110 5 .27 4.625 mg/L 87 90 110 .27 .347 mg/L 5 4.732 mg/L 95 90 110 25 20 M2 RA Iron, total recoverable M200.7 ICP ACZ ID Type Analyzed PCN/SCN QC Sample Found Units Rec Lower Upper RPD Limit Qual WG390035 WG3900351CV ICV 09/09/15 15:14 11150811-1 2 1.956 mg/L 98 95 105 WG3900351CB ICB 09/09/15 15:20 U mg/L -0.06 0.06 WG389852LRB LRB 09/09/15 15:33 U mg/L -0.044 0.044 WG389852LFB LFB 09/09/15 15:36 11150901-3 1.0001 .99 mg/L 99 85 115 L26281-01LFM LFM 09/09/15 15:42 11150901-3 1.0001 .14 1.146 mg/L 101 70 130 L26281-01LFMD LFMD 09/09/15 15:45 11150901-3 1.0001 .14 1.14 mg/L 100 70 130 1 20 L26281-1510021536 Page 7 of 19 ACZ Laboratories, Inc. 2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493 Pinnacle Water Inc. Inorganic QC Summa ACZ Project ID: L26281 Lead, total recoverable M200.8 ICP -MS ACZ ID Type Analyzed PCN/SCN QC Sample Found Units Rec Lower Upper RPD Limit Qual WG390565 WG390565ICV ICV 09/16/15 20:33 MS150902-7 .05 .05255 mg/L 105 90 110 WG390565ICB ICB 09/16/15 20:36 U mg/L -0.0003 0.0003 WG390469LRB LRB 09/16/15 20:40 U mg/L -0.00022 0.00022 WG390469LFB LFB 09/16/15 20:43 MS150827-2 .05005 .0484 mg/L 97 85 115 L26396-12LFM LFM 09/16/15 21:01 MS150827-2 .05005 .0005 .04999 un9/1- 99 70 130 L26396-12LFMD LFMD 09/16/15 21:04 MS150827-2 .05005 .0005 .04931 mg/L 98 70 130 1 20 Magnesium, dissolved M200.7 ICP ACZ ID Type Analyzed PCN/SCN QC Sample Found Units Rec Lower Upper RPD Limit Qual WG390235 WG3902351CV ICV 09/11/15 19:17 11150811-1 100 98.19 mg/L 98 95 105 WG3902351CB ICB 09/11/15 19:23 .26 mg/L -0.6 0.6 WG390235LFB LFB 09/11/15 19:35 11150901-3 50.00416 49.12 mg/1- 98 85 115 L26371-01AS AS 09/11/15 19:48 11150901-3 50.00416 1.3 50.09 mg/L 98 85 115 L26371-01ASD ASD 09/11/15 19:51 11150901-3 50.00416 1.3 49.44 mg/L 96 85 115 1 20 Manganese, total recoverable M200.7 ICP ACZ ID Type Analyzed PCN/SCN QC Sample Found Units Rec Lower Upper RPD Limit Qual WG390035 WG3900351CV ICV 09/09/15 15:14 11150811-1 WG3900351CB ICB 09/09/15 15:20 WG389852LRB LRB 09/09/15 15:33 WG389852LFB LFB 09/09/15 15:36 11150901-3 L26281-01 LFM LFM 09/09/15 15:42 11150901-3 L26281-01 LFMD LFMD 09/09/15 15:45 11150901-3 2 1.967 mg/L 98 95 105 U mg/L -0.015 0.015 U mg/L -0.011 0.011 .499 .4904 mg/L 98 85 115 .499 U .4995 mg/L 100 70 130 .499 U .4971 1110/1- 100 70 130 0 20 Nitrate/Nitrite as N M353.2 - H2SO4 preserved ACZ ID Type Analyzed PCN/SCN QC Sample Found Units Rec Lower Upper RPD Limi WG390186 WG3901861CV ICV 09/10/15 18:49 W1150723-7 2.416 WG3901861CB ICB 09/10/15 18:50 WG390191 WG390191 LFB LFB 09/10/15 22:17 L26249-01AS AS 09/10/15 22:19 L26249-02DUP DUP 09/10/15 22:22 2.402 mg/L 99 U mg/L 90 110 -0.06 0.06 W 1150613-3 2 1.961 mg/L 98 90 110 W1150613-3 2 1.32 3.311 mg/L 100 90 110 1.33 1.325 mg/L 0 20 pH (lab) SM4500H+ B ACZ ID Type Analyzed PCN/SCN QC Sample Found Units Rec Lower Upper RPD Limit Qual WG389508 WG389508LCSW1 LCSW 08/29/15 10:04 PCN46943 L26341-01DUP DUP 08/29/15 11:58 WG389508LCSW4 LCSW 08/29/15 13:41 PCN46943 WG389508LCSW7 LCSW 08/29/15 17:13 PCN46943 WG389508LCSW10 LCSW 08/29/15 20:18 PCN46943 WG389508LCSW13 LCSW 08/29/15 23:24 PCN46943 6.01 6.1 units 101 5.9 6.1 8.1 8.1 units 6.01 6.1 units 101 5.9 6.1 6.01 6.1 units 101 5.9 6.1 6.01 6.1 units 101 5.9 6.1 6.01 6.1 units 101 5.9 6.1 0 20 L26281-1510021536 Page 8 of 19 ACZ Laboratories, Inc. 2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493 Pinnacle Water Inc. Inorganic QC Summary ACZ Project ID: L26281 Residue, Filterable (TDS) @180C SM2540C ACZ ID Type Analyzed PCN/SCN QC Sample Found Units Rec Lower Upper RPD Limit Qual WG389423 WG389423PBW PBW 08/28/15 10:00 WG389423LCSW LCSW 08/28/15 10:02 PCN49005 L26325-02DUP DUP 08/28/15 10:34 U mg/L 260 264 mg/L 102 80 120 -20 20 474 472 mg/L 0 10 Sodium, dissolved M200.7 ICP ACZ ID Type Analyzed PCN/SCN QC Sample Found Units Rec Lower Upper RPD Limit Qual WG390235 WG3902351CV ICV 09/11/15 19:17 11150811-1 100 96.35 mg/L 96 95 105 WG3902351CB ICB 09/11/15 19:23 U mg/L -0.6 0.6 WG390235LFB LFB 09/11/15 19:35 11150901-3 100.0581 96.75 mg/L 97 85 115 L26371-01AS AS 09/11/15 19:48 11150901-3 100.0581 359 441.4 mg/L 82 85 115 L26371-01ASD ASD 09/11/15 19:51 11150901-3 100.0581 359 441.4 mg/L 82 85 115 0 20 M3 M3 Sulfate D516-02/-07 - Turbidimetric ACZ ID Type Analyzed PCN/SCN QC Sample Found Units Rec Lower Upper RPD Limit Qual WG390223 WG3902231CB ICB 09/11/15 10:05 U mg/L -3 3 WG3902231CV ICV 09/11/15 10:05 W1150903-1 20 20 mg/L 100 90 110 WG390223LFB LFB 09/11/15 10:50 W1150904-1 10.01 9.5 mg/L 95 90 110 L26249-01DUP DUP 09/11/1511:15 2210 2250 mg/L L26249-02AS AS 09/11/1511:15 SO4TURB2OX 50 2370 2460 mg/L 180 90 110 2 20 M3 Uranium, total recoverable M200.8 ICP -MS ACZ ID Type Analyzed PCN/SCN QC Sample Found Units Rec Lower Upper RPD Limit Qual WG390565 WG3905651CV ICV 09/16/15 20:33 MS150902-7 .05 .05059 mg/L 101 90 110 WG3905651CB ICB 09/16/15 20:36 U mg/L -0.0003 0.0003 WG390469LRB LRB 09/16/15 20:40 U mg/L -0.00022 0.00022 WG390469LFB LFB 09/16/15 20:43 MS150827-2 .05 .04691 mg/L 94 85 115 L26396-12LFM LFM 09/16/15 21:01 MS150827-2 .05 .0015 .05177 mg/L 101 70 130 L26396-12LFMD LFMD 09/16/15 21:04 MS150827-2 .05 .0015 .05123 mg/L 99 70 130 1 20 Zinc, total recoverable M200.7 ICP ACZ ID Type Analyzed PCN/SCN QC Sample Found Units Rec Lower Upper RPD Limit Qual WG390035 WG3900351CV ICV 09/09/15 15:14 11150811-1 2 1.924 mg/L 96 95 105 WG3900351CB ICB 09/09/15 15:20 U mg/L -0.03 0.03 WG389852LRB LRB 09/09/15 15:33 U mg/L -0.022 0.022 WG389852LFB LFB 09/09/15 15:36 11150901-3 .4995 .469 mg/L 94 85 115 L26281-01LFM LFM 09/09/15 15:42 11150901-3 .4995 U .475 mg/L 95 70 130 L26281-01LFMD LFMD 09/09/15 15:45 11150901-3 .4995 U .467 mg/L 93 70 130 2 20 L26281-1510021536 Page 9 of 19 ACZ Laboratories, Inc. 2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493 Inorganic Extended Qualifier Report Pinnacle Water Inc. ACZ Project ID: L26281 ACZ ID WORKNUM PARAMETER METHOD QUAL DESCRIPTION L26281-01 WG390235 Sodium, dissolved WG390247 Chloride RG557603 Corrosivity (calc.) WG389930 Fluoride M200.7 ICP SM4500CI-E SM 2330 - CaCO3 SI SM4500F-C M3 The spike recovery value is unusable since the analyte concentration in the sample is disproportionate to the spike level. The recovery of the associated control sample (LCS or LFB) was acceptable. M3 The spike recovery value is unusable since the analyte concentration in the sample is disproportionate to the spike level. The recovery of the associated control sample (LCS or LFB) was acceptable. ZZ Laboratory measured pH and temperature were used in this calculation. Sampler did not report either field pH, field temperature, or both. M2 Matrix spike recovery was low, the recovery of the associated control sample (LCS or LFB) was acceptable. SM4500F-C RA Relative Percent Difference (RPD) was not used for data validation because the sample concentration is too low for accurate evaluation (< 10x MDL). WG389423 Residue, Filterable (TDS) @180C SM2540C N1 See Case Narrative. WG390223 Sulfate D516-02/-07 - Turbidimetric M3 The spike recovery value is unusable since the analyte concentration in the sample is disproportionate to the spike level. The recovery of the associated control sample (LCS or LFB) was acceptable. REPAD.15.06.05.01 L26281-1510021536 Page 10 of 19 ADZ Laboratories, Inc. 2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493 Pinnacle Water Inc. Project ID: Sample ID: SUMA Locator: RadioChemistry Analytical Results ACZ Sample ID: Date Sampled: Date Received: Sample Matrix: L26281-01 08/25/15 14:20 08/26/15 Ground Water Gross Alpha & Beta, total M900.0 Prep Method: Parameter Measure Date Prep Date Result Error(+l-) LLD Units XQ Gross Alpha Gross Beta 09/28/15 0:27 09/28/15 0:27 -1 2.4 2.1 2.6 3.9 5.6 pCi/L pCi/L kls kls REPRC.02.06.05.01 Please refer to Qualifier Reports for details. L26281-1510021536 Page 11 of 19 ACZ Qualifiers (Qual) ADZ Laboratories, Inc. 2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493 Radiochemistry Reference Report Header Explanations Batch A distinct set of samples analyzed at a specific time Error(+/-) Calculated sample specific uncertainty Found Value of the QC Type of interest Limit Upper limit for RPD, in %. LCL Lower Control Limit, in % (except for LCSS, mg/Kg) LLD Calculated sample specific Lower Limit of Detection PCN/SCN A number assigned to reagents/standards to trace to the manufacturer's certificate of analysis PQL Practical Quantitation Limit QC True Value of the Control Sample or the amount added to the Spike Rec Amount of the true value or spike added recovered, in % (except for LCSS, mg/Kg) RER Relative Error Ratio, calculation used for Dup. QC taking into account the error factor. RPD Relative Percent Difference, calculation used for Duplicate QC Types UCL Upper Control Limit, in % (except for LCSS, mg/Kg) Sample Value of the Sample of interest QC Sample Types DUP LCSS LCSW Sample Duplicate Laboratory Control Sample - Soil Laboratory Control Sample - Water MS/MSD PBS PBW Matrix Spike/Matrix Spike Duplicate Prep Blank - Soil Prep Blank - Water QC Sample Type Explanations Blanks Control Samples Duplicates Matrix Spikes Verifies that there is no or minimal contamination in the prep method procedure. Verifies the accuracy of the method, including the prep procedure. Verifies the precision of the instrument and/or method. Determines sample matrix interferences, if any. H Analysis exceeded method hold time. Method Prefix Reference M SM D RP ESM EPA methodology, including those under SDWA, CWA, and RCRA Standard Methods for the Examination of Water and Wastewater. ASTM DOE DOE/ESM Comments (1) (2) (3) (4) Solid matrices are reported on a dry weight basis. Preparation method: "Method" indicates preparation defined in analytical method. QC results calculated from raw data. Results may vary slightly if the rounded values are used in the calculations. An asterisk in the "XQ" column indicates there is an extended qualifier and/or certification qualifier associated with the result. For a complete list of ACZ's Extended Qualifiers, please click: http://www.acz.com/public/extquallist.pdf REP003.09.12.01 L26281-1510021536 Page 12 of 19 ACZ Laboratories, Inc. 2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493 Pinnacle Water Inc. Radiochemistry QC Summary ACZ Project ID: L26281 Alpha M900.0 Units: pCi/L ACZ ID Type Analyzed PCN/SCN QC Sample Error LLD Found Error LLD Rec Lower Upper RPD/RER Limit Qual WG391252 WG390791PBW PBW 09/28/15 WG390791LCSW LCSW 09/28/15 PCN48198 L26181-02 DUP DUP-RER 09/28/15 L26218-01 DUP DUP-RER 09/28/15 L26181-02 MS MS 09/28/15 PCN48198 -.18 1.1 1.2 2.4 100 120 10 1.8 120 83 133 8.3 10 9.2 18 12 9.1 0.62 1.1 2.8 2.6 1.1 2.7 2.7 0 250 8.3 10 9.2 180 31 9.4 69 83 133 Beta M900.0 2 2 M2 Units: pCi/L ACZ ID Type Analyzed PCN/SCN QC Sample Error LLD Found Error LLD Rec Lower Upper RPD/RER Limit Qua! WG391252 WG390791PBW PBW 09/28/15 WG390791LCSW LCSW 09/28/15 PCN44693 L26181-02 DUP DUP-RER 09/28/15 L26218-01 DUP DUP-RER 09/28/15 L26218-01 MS MS 09/28/15 PCN44693 -1.1 2.5 3.4 100 110 8.9 5.7 110 70 129 41 14 16 28 15 16 1.5 4.8 6 .98 4.2 5.8 100 1.5 4.8 6 96 8.7 6 95 70 129 6.8 0.63 2 0.08 2 L26281-1510021536 Page 13 of 19 ACZ Laboratories, Inc. 2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493 Pinnacle Water Inc. RadChem Extended Qualifier Report ACZ Project ID: L26281 ACZ ID WORKNUM PARAMETER METHOD QUAL DESCRIPTION L26281-01 WG391252 Gross Alpha M900.0 M2 Matrix spike recovery was low, the recovery of the associated control sample (LCS or LFB) was acceptable. REPAD.15.06.05.01 L26281-1510021536 Page 14 of 19 ACZ Laboratories, Inc. 2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493 Certification Qualifiers Pinnacle Water Inc. ACZ Project ID: L26281 No certification qualifiers associated with this analysis REPAD.05.06.05.01 L26281-1510021536 Page 15 of 19 ACZ Laboratories, Inc. 2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493 Pinnacle Water Inc. Sample Receipt ACZ Project ID: L26281 Date Received: 08/26/2015 09:41 Received By: ddp Date Printed: 8/26/2015 Receipt Verification 1) Is a foreign soil permit included for applicable samples? 2) Is the Chain of Custody or other directive shipping papers present? 3) Does this project require special handling procedures such as CLP protocol? 4) Are any samples NRC licensable material? 5) If samples are received past hold time, proceed with requested short hold time analyses? 6) Is the Chain of Custody complete and accurate? 7) Were any changes made to the Chain of Custody prior to ACZ receiving the samples? A change was made in the ID Line 1 section prior to ACZ custody. YES NO NA X X X X X X X Samples/Containers 8) Are all containers intact and with no leaks? 9) Are all labels on containers and are they intact and legible? 10) Do the sample labels and Chain of Custody match for Sample ID, Date, and Time? 11) For preserved bottle types, was the pH checked and within limits? 1 12) Is there sufficient sample volume to perform all requested work? 13) Is the custody seal intact on all containers? 14) Are samples that require zero headspace acceptable? 15) Are all sample containers appropriate for analytical requirements? 16) Is there an Hg -1631 trip blank present? 17) Is there a VOA trip blank present? 18) Were all samples received within hold time? YES NO NA X X X X X X X X X Chain of Custody Related Remarks Client Contact Remarks Shipping Containers Cooler Id 1221 Temp (°C) 5.8 Rad (pR/Hr) 15 Custody Seal Intact? Yes Was ice present in the shipment container(s)? Yes - Wet ice was present in the shipment container(s). Client must contact an ACZ Project Manager if analysis should not proceed for samples received outside of their thermal preservation acceptance criteria. REPAD LPII 2012-03 L26281-1510021536 Page 16 of 19 ADZ Laboratories, Inc. 2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493 Pinnacle Water Inc. Sample Receipt ACZ Project ID: L26281 Date Received: 08/26/2015 09:41 Received By: ddp Date Printed: 8/26/2015 1 The preservation of the following bottle types is not checked at sample receipt: Orange (oil and grease), Purple (total cyanide), Pink (dissolved cyanide), Brown (arsenic speciation), Sterile (fecal coliform), EDTA (sulfite), HCI preserved vial (organics), Na2S2O3 preserved vial (organics), and HG -1631 (total/dissolved mercury by method 1631). REPAD LPII 2012-03 L26281-1510021536 Page 17 of 19 c L ADZ Laboratories, Inc 1 2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-14-9 Report to: , Name: gOF:: /i:(:))E) ,g . CHAIN Address: toi -kre....ORkc.,., of CUSTODY Company: Q't 00 f\- c_,W_ \,\A.-cE..g.epc-P—ZoN1 c-) 1 Ns. k E_ , Cr g L, a,3 E-mail: RD0 14f.)1riLkky e P, N3 Ts) A Ektj (vrEg ,Ccon Telephone: <1.10 Copy of Report to: E-mail: Name: Company: Telephone: Invoiceto: Name: goB D000akk,/ HT remains short ACZ will Address: Il0-1 t -A -E -43D -i-4-1/4‹. ok Company: 4).,/,,,,,,N6E. L.) pc-Trz.g ciP,--[6.01:.-31)4C Co E-mail: RpoN (s)1...-81.1 & p, 0 ,,, f.,\.€,,,,,,\TE& , ,,,,,,,, i Telephone: cno -ci b 3 1 If sample(s) received past holding time (HT), or if insufficient 1 analysis before expiration, shall ACZ proceed with requested I If "NO" then ACZ will contact client for further instruction. If neither "YES" nor "NO" is indicated, to complete HT analyses? proceed with the requested analyses, even if HT is expired, YES NO and data will be qu lified Are samples for SDWA Compliance Monitoring? Yes If yes, please include state forms. Results will be reported to PQL for Colorado. No I><1 Samplers Name': "Sampler's Signature: PROJECT INFORMATION Quote #: SCk0Api 60e, i)01,hvd \ ,f Sam ers Site Information I attest to 0 r tampering the authent with the sample State e... 0 Zip code understand and punishable 5? 1 (013 Time Zone the quote number) 01T-1-4 *-P-A-N*52) city and validity in anyway, 12 0 ._ 03 c 0 0 46 t of this is considered '. ANALYSES -5 -v.\' sample. I fraud REQUESTED that intentionally by State (attach Mist mislabeling Law. or use time/date/location or PO#: I 1 Reporting state for compliance testing: LO Check box if samples include NRC licensed material? SAMPLE IDENTIFICATION 44)44r___trl.c.i.E4_ DATE:TIME Matrix >( Gu) (I) >< Matrix SW (Surface Water) • GW (Ground Water) • WW (Waste Water) • DW (Drinking Wate ) • SL (Sludge) • SO (Soil) • OL (Oil) • Othe (Specify) REMARKS Please refer to ACZ's terms & conditions located on the reverse side of this COC. RELINQUISHEOBY: . DATE:TIME . . RECEIVED BY: . .• DATE:TIME Do00 _./ s --is' --oc,( r n fl A A I -A n flfli r - ,r , - - A (1 - . [ A Il White - Return with sample. Yellow - Retain for your records. );PACK' Laboratories, Inc. 2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493 Account: PINNACLE/Pinnacle Water Inc. Bottle Order: B034046 Bill to Account: Bill to ACZ Ship Date Requested: 08/21/2015 Request Placed at: 08/20/2015 14:56 Service Requested: UPS Ground Sampling supplies 1 COC 2 SEAL 1 RETURN 6 LABELS Chain of Custody Custody Seal Return Address Sample Labels Chain of Custody, 1 for 10 samples. Custody seals for cooler, two for each cooler. Return Address label, one for each cooler. ACZ supplied labels for sample containers ACZ Coolers K ei a. st?s�s.:ti:ka PSTracking,Number;t ;fi. ;1°! 1 1221 Small 6 1Z8101300375066246 Quote number: SUMA Sample Quantity: 1 1 Sample, Annual Analysis of Groundwater for CDPHE Deluxe ACZ is responsible for necessary sample filtering F,'Itern3001Preserve 11iitructio4 1 GREEN 1 RAW 125 ML Filtered/Nitric 500 ML Raw fir, Metals (dissolved except ICPMS) - This is a filtered sample. Completely fill container. Wet Chemistry (analyses that do not require preservative or filtration) - Completely fill container. 1 RED PC 250 ML Red pre -cleaned Metals (total including ICPMS) - Do not overfill as there is Nitric Raw/Nitric Acid in the bottle. 1 RED RAD 1000 ML Raw/Nitric Radiochemistry (total) - Do not overfill as there is Nitric Acid in the bottle. 1 WHITE 250 ML Filtered Wet chemistry (dissolved) - This is a filtered sample. Completely fill container. 1 YELLOW 250 ML Raw/Sulfuric For total wet chemistry analyses. Do not overfill as there is Sulfuric Acid in the bottle. Prepared By/Date: mjj L26281-1510021536 Page 1 of 2 Page 19 of 19