HomeMy WebLinkAboutEx 07a Wright Water Engineers Water Report Pages 86-119EXHIBiT jim
TO
LIMITED IMPACT REVIEW
FOR STORAGE AND rABRDCATD N FACIlLynY
(lin ,k ding Request for Suibdhi mm la Amendment)
Parcel ID No. 2393-274-01-004
Page 086
Wright Water Engineers, Inc.
818 Colorado Avenue, Suite 307, P.O. Box 219
Glenwood Springs, Colorado 81602
(970) 945-7755 TEL
(970) 945-9210 FAX
July 10, 2018
Via Email
Wes Grammer
GO Self Storage
P.O. Box 22876
Kansas City, MO 64113
Re: Water Supply Evaluation for Proposed GO Self Storage Facility
Dear Mr. Grammer:
www,wrightwater.com
e-mail: jkelly@wrightwater.com
Wright Water Engineers, Inc. (WWE) has prepared this letter report to document the methodology
used to estimate the daily water demands for the proposed GO Self Storage facility. In addition,
we evaluated the adequacy of the physical water supply to meet the proposed water demands. The
project is proposed to be developed on Parcel C of the Dixon Subdivision at 12744 Highway 82 in
Garfield County, Colorado. The well for the self -storage facility is located on Lot A of the Dixon
Subdivision. The Improvement Survey Plat is attached to show the locations of the lots and the
well.
WATER DEMAND
The water uses associated with the proposed self -storage facility include three bathrooms, an
employee kitchen, and a vehicle washbay. To estimate the daily water demand associated with
these uses, WWE consulted the Garfield County On -Site Wastewater Treatment System (OWTS)
Regulations. Table 6-2 of the Regulations provided estimates of average daily wastewater flow
for various uses in gallons per day (gpd). While Table 6-2 does not provide estimates for the exact
uses associated with the proposed self -storage facility, WWE was able to use the table as a guide
and used engineering judgment for the best fits.
The estimated wastewater flow for each restroom was based on a residential lavatory (sink) and
water closet (toilet) with rates of 8.4 and 24.8 gpd, respectively. With each of the three restrooms
rated at 33.2 gpd, all three total to an estimated 99.6 gpd of wastewater flow.
The employee kitchen was based on a residential kitchen with a dishwasher (1.8 gpd) and kitchen
sink (5.8 gpd) for a total wastewater flow of 7.6 gpd. The vehicle washbay was assumed to be
equivalent to two utility sinks, each at 8.4 gpd, for a total of 16.8 gpd.
Therefore, the total estimated wastewater flow for the proposed facility is 124 gpd. Assuming that
90 percent of the water used at the facility becomes wastewater (10 percent consumption), the
water demand for the facility is 137.8 gpd, or rounding up to 140 gpd.
DENVER DURANGO
(303) 480-1700 TEL (303) 480-1020 FAX (970) 259.7411 TEL (970) 259.8758 FAX
Page 087
Mr. Wes Grammer
July 10, 2018
Page 2
WWE did a literature search to verify the reasonableness of the water demand of 140 gpd, or 0.157
acre-feet per year. We found values of 0.13 to 0.174 acre-feet per year for similar facilities;
however, these estimates were typically dominated by outdoor use for landscape irrigation. For
example, of the annual demand of 0.174 acre-feet, only 0.024 acre-feet was for indoor use.
Therefore, we conclude that our estimate is very conservative due to outdoor irrigation demand
being satisfied by the irrigation ditch.
WATER SUPPLIES
The property is served by the TePoel Well operating under Permit No. 45419-F-R (see attached)
located on Lot A of the Dixon Subdivision. The permit allows for pumping at a rate of up to 30
gallons per minute (gpm), and "the use of ground water from this well is limited to drinking and
sanitary purposes and the irrigation of 0.70 acres [sic] of landscaping/agricultural materials at the
Planted Earth." Historically, the well served a single-family residence and various uses and
facilities associated with the Planted Earth nursery and greenhouse. The property has shares in the
Lower Kelso Ditch Company, and the Kelso Ditch is the primary source of irrigation water for the
exiting nursery and greenhouse.
The existing well was drilled by Shelton Drilling on March 9, 2001 (see attached Well
Construction and Test Report). The well was drilled to a total depth of 141 feet encountering
Maroon Formation from depths of 74 feet to TD. The well was completed with perforated casing
in the bottom 40 feet of the well. The static water level at the time of drilling was 80 feet.
For the proposed facility, all potable uses will come from the TePoel Well and all landscape
irrigation will be provided by the Kelso Ditch. The water demand of the facility estimated at 140
gpd will be served by the well, which may also continue to serve the historical uses on the three
lots.
WELL YIELD
A 20-gpm pump was installed by Samuelson Pump Company on April 19, 2001 (see attached
Pump installation and Test Report). A pumping test was performed on April 20, with a static water
level of 82 feet, 4 inches. After pumping for an unknown time at 20 gpm, the water level was 83
feet, 21/2 inches.
WWE conducted a pumping test on the well on May 31, 2018. The well plumbing was configured
such that the well would cycle on to fill three pressure tanks and then cycle off while the tanks
emptied. Based on previous tests showing little drawdown, we determined that a 4-hour test would
likely be adequate.
Prior to starting the pumping test, the initial water level was 69.20 feet below the top of casing. The
pumping test was started at 10:15 am. The pumping test was performed by closing all valves to the
remainder of the property except for the pressure tanks. A hose was connected to a bib at the pressure
tank and turned on. A flow rate was also established by measuring the time it took to fill a 15-gallon
bucket from the hose. The discharge was approximately 10 to 12 gallons per minute.
Page 088
Mr. Wes Grammer
July 10, 2018
Page 3
For the first hour of the pumping test, a water level was acquired in the well, with the use of a
water level indicator. A measurement was taken about every minute and noted. During the
pumping test when the pump would cycle on, the water level would drop approximately 10 inches
and then maintain a constant depth. Once the pump would turn off, the water level would return
relatively quickly to where it was before the pump turned on. Figure 1 is a graph showing the
water level measurement during the pumping test.
The test was continued for another 3 hours until approximately 2:15 pm. During that time, the
water level was evaluated to verify there had not been any changes. During the last 15 minutes of
the pumping test, the water levels were evaluated once more and determined the same drawdown
and recover were taking place to a static water level of 69.40 feet below the top of casing. Since
recovery of the water level was almost immediate, there was no need to continue to monitor the
water level after the test had been completed. WWE estimated that between 2,400 and 2,880
gallons were pumped during the four-hour test.
The current property owner provided well meter readings from water year 2016 (See Table 1).
The records indicate the winter time use of about 1,070 gpd, then the water use ramping up to a
maximum of 6,345 gpd in June. It is unclear whether the additional use included irrigation, or just
additional uses associated with the nursery and greenhouse operation during the irrigation season.
Regardless, the data show that the well has demonstrated it is capable of supplying a water demand
in excess of 6,000 gpd.
WELL WATER QUALITY
WWE collected water quality samples for Iaboratory analysis near the end of the pumping test.
The suite of parameters tested are a subset of those parameters that have drinking water standards
that WWE typically uses for private well water supplies.
Table 2 summarizes the laboratory results for the well water. As shown in the table, none of the
parameters had a detected level that exceeded the primary or secondary standards, where
applicable. The water had a hardness of 344 mg/L, which is typical of well water completed in
bedrock. A water softener would be recommended to reduce scaling on pipes. The total dissolved
solids (TDS) was also high at 492 mg/L, making the water marginal for irrigation. Both of these
parameters are purely aesthetic and have no adverse health risk.
CONCLUSION
The water demand associated with the proposed self -storage facility is conservatively estimated to
be 140 gpd. The well has demonstrated both historically and during our pumping test to be able
to satisfy a demand far in excess of the proposed demand. Therefore, even if historical uses
continue on Lot A and Parcel D, the well will be able to provide an adequate physical supply,
especially since the outdoor irrigation uses will be satisfied via the Kelso Ditch. The water quality
of the well water showed good water quality with the only treatment needed for aesthetic purposes
and disinfection.
Page 089
Mr. Wes Grammer
July 10, 2018
Page 4
Please do not hesitate to call if you have any questions.
Very truly yours,
W' Hi WATER G RS, INC.
By
nathan M. Kel , P.' .
enior Water Reso 1-s Engineer
Attachments: SGM Improvement Survey Plat
Well Permit No. 45419-F-R
Well Construction and Test Report
Pump Installation and Test Report
Figure 1 -- Water Level Measurement
Table 1— 2016 Well Meter Readings
Table 2 — Water Quality Analysis
ACZ Laboratories Water Quality Report
cc: Doug Pratte, The Land Studio
O:1IVWE418I-05310001Docs\GO Self Storage Water Suppiy.docx
Page 090
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Page 094
-68.8
-69
-69.2
-69.4
-69.8
-70
-70.2
-70.4
FIGURE 1
GO Self Storage - TePoel Well
Water Level Measurement May 31, 2018
4 4 4 `s 4 P`� P`s P`s P4 P4 P4 P4 P4 P`s P`s P`s P4 P`s P`� P`� P4 P`s P`� P`� P`S P4 P`� P`� P. P4 P4 P`� P4 4
'yh h1 i°) .1> .tip tia .12 ti$ .tip 0,3='),1 0 0 ,av .4,°' hb� hb.5g � . O .O OG' .CC) CP
y0' 0 O .•O yo y0 y0 do Nr y0 yo 'r 0 ^r ,y0 y0 y0 y0 tiD ,30 y4 y0 ^). 0 yo 0 do 0 y. }ti• ti.
Time
G:1W W E1181-05310001Engr\Pumping Test1 Wright Water Engineers, Inc.
Water Level 0ata.xlsx
July 10, 2018
Prepared By: MO
Checked By: SAS
GO Self Storage - TePoel Well
Well Water Level Measurement - May 31, 2018
Time
Water Level
(ft)
Note
10:15:00 AM
69.21
Pump off
10:17:04 AM
69.21
Pump on
10:17:38 AM
69.8
10:19:10 AM
70.1
Pump off
10:19:40 AM
69.35
10:20:40 AM
69.31
10:21:30 AM
69.28
10:23:07 AM
69.27
Pump on
10:23:34 AM
69.92
10:23:46 AM
70
10:24:08 AM
70.05
10:25:07 AM
70.08
Pump off
10:25:49 AM
69.41
10:27:12 AM
69.3
10:28:59 AM
69.28
Pump on
10:29:13 AM
69.8
10:29:47 AM
70
_
10:30:00 AM
70.1
10:31:01 AM
70.17
Pump off
10:32:50 AM
69.7
10:33:07 AM
69.3
10:34:22 AM
69.28
10:34:56 AM
69.2
Pump on
10:35:52 AM
70.03
10:36:21 AM
70.08
10:37:04 AM
70.15
Pump off
10:37:39 AM
69.4
10:39:21 AM
69.33
10:40:22 AM
69.3
10:41:04 AM
69.28
Pump on
10:41:31 AM
70
10:42:17 AM
70.1
10:43:03 AM
70.12
Pump off
10:43:49 AM
69.4
G:\WUJE\181-0531000\Engr\Pumping Test\
Water Level Data.xlsx
Time
Water Level
(ft)
Note
10:46:33 AM
69.31
10:46:52 AM
69.3
Pump on
10:47:24 AM
70
10:47:40 AM
70.05
10:48:25 AM
70.1
10:49:10 AM
70.11
Pump off
10:49:37 AM
69.5
10:49:52 AM
69.4
10:51:19 AM
69.32
10:52:52 AM
69.3
Pump on
10:53:23 AM
70
10:53:55 AM
70.1
10:54:56 AM
70.11
Pump off
10:55:32 AM
_ 69.45
10:55:58 AM
69.4
10:57:03 AM
69.35
10:58:01 AM
69.31
Pump on
10:58:50 AM
69.31
10:59:17 AM
69.91
10:59:25 AM
70
10:59:32 AM
70.05
10:59:50 AM
70.1
11:00:55 AM
70.13
Pump off
11:01:50 AM
69.4
11:02:59 AM
69.35
11:04:11 AM
69.32
11:04:47 AM
69.32
Pump on
11:05:06 AM
69.9
11:05:26 AM
70
11:05:44 AM
70.1
11:06:49 AM
70.13
Pump off
11:07:18 AM
69.5
11:08:01 AM
69.4
Page 096
TABLE 1
HIPA HIPA LLC
WATER RIGHTS DIVERSIONS
Year: 2016
MONTH
DAY
METER
READING
DIVERSION AMOUNT
GALLONS
GALLONS PER DAY
ACRE FEET
NOVEMBER '15
1
2,480,390
DECEMBER'15
3
2,510,400
30,010
1,072
0.09
JANUARY
-
0
0.00
FEBRUARY
-
0
0.00
MARCH
-
0
0.00
APRIL
5
2,630,201
119,801
4,792
0.37
MAY
2,720,406
90,205
2,910
0.28
JUNE
2,910,765
190,359
6,345
0.58
JULY
3,000,295
89,530
2,888
0.27
AUGUST
3,050,775
50,480
1,628
0.15
SEPTEMBER
3,104,325
53,550
1,785
0.16
OCTOBER
31
3,207,300
102,975
3,322
0.32
G:IW W E1181-05310001EngrlDiversion Records
2016 Diversions,xlsx
Page 097
TABLE 2
GO Self Storage - Water Quality Analysis
Sampled on May 31, 2018
ANALYTE
UNITS
Method
Tepoel Well
_MCL1
MCLG2
SMCL3
Aluminum (Total)
mg/L
EPA 200.7
<0.03
0.050-0.2
Antimony (Total)
mg/L
EPA 200.8
<0.0004
0.006
0.006
Arsenic (Total)
mg/L
EPA 200.8
0.001
0.010
0
Barium (Totai)
mg/L
EPA 200.7
0.020
2
2
Beryllium (Total)
mg/L
EPA 200.8
<0.00005
0.004
0.004
Cadmium (Total)
mg/L
EPA 200.7
<0.005
0.005
0.005
Calcium (Dissolved)
mg/L
EPA 200.7
84.3
Chromium (Dissolved)
mg/L
mg/L
EPA 200.7
<0.01
0.1
0.1
Copper (Total)
EPA 200.7
<0.01
1.3
1.3
1.0
Iron (Total)
mg/L
EPA 200.7
<0.02
0.3
Lead (Total)
mg/L
EPA 200.8
0.0005
0.015
0
Magnesium (Dissolved)
mg/L
EPA 200.7
32.5
Manganese (Total)
mg/L
EPA 200.7
<0.005
0.05
Mercury (Total)
mg/L
EPA 245.1
<0.0002
0.002
0.002
Nickel (Total)
mg/L.
EPA 200.7
<0.008
0.1
Potassium (Dissolved)
mg/L
EPA 200.7
2.4
Selenium (Total)
mg/L
EPA 200.8
0.002
0.05
0.05
Silica (Dissolved)
mg/L
EPA 200.7
27.1
Silver (Total)
mg/L
EPA 200.7
<0.01
0.10
Sodium (Dissolved)
mg/L
EPA 200.7
38,0
Thallium (Total)
mg/L
EPA 200.8
<0.0001
0.002
0.0005
Uranium
mg/L
EPA 200.8
0.0091
Zinc (Total)
mg/L
EPA 200.7
<0.01
5
Alkalinity, Total as CaCO3
mg/L
SM2320B
267
Chloride
mg/L
SM4500CI-E
10.8
250
Corrosivity, Langelier Index
SM 2330
1.1
Cyanide, Total
mg/L
EPA 335.4
<0.003
0.2
0.2
Fluoride
mg/L
SM4500E-C
0.44
4
4
2
Hardness, Total as CaCO3
mg/L
SM 2340B
344
10
10
Nitrogen, Nitrate
mg/L
NO3NO2-NO2
0.89
Nitrogen, Nitrate}Nitrite
mg/L.
EPA 353.2
0.89
Nitrogen, Nitrite
mg/L
EPA 353.2
<0.01
1
1
pH
su
SM4500H+B
8.2
6.5-8.5
Phosphorus, Total
mg/L
EPA 365.1
<0.02
Solids, Total Dissolved
mg/L
SM254OC
492
Solids, Total Suspended
mg/L
SM2540D
<5
Specific Conductivity
umhos/cm
SM2510B
754
Sulfate
mg/L
SM4500 SO4-D
130
250
Turbidity
NTU
EPA 180.1
<0.1
0.5
Gross Alpha
pC1/L
7.3
15
Gross Beta
pCi/L
3.3
50
1Maximum Contaminant Level (MCL) - The highest level of a contaminant that is allowed in drinking water.
MCLs are set as close to MCLGs as feasible using the best available treatment technology and taking
cost into consideration. MCLs are enforceable standards.
2Maximum Contaminant Level Goal (MCLG) - The level of a contaminant in drinking water below which there is
no known or expected risk to health. MCLGs allow for a margin of safety and are non -enforceable
public health goals.
3National Secondary Drinking Water Regulations (NSDWRs or secondary standards) are non -enforceable
guidelines regulating contaminants that may cause cosmetic effects (such as skin or tooth discoloration)
or aesthetic effects (such as taste, odor, or color) in drinking water. EPA recommends secondary
standards to water systems but does not require systems to comply.
G:1WWE4161-05310001Engr\Waterflualityl Wright Wafer Engineers, Inc.
Table 2 WQ Results.xlsx July 10, 2018
Prepared By: MO
Checked By: JMK
Page 098
ADZ Laboratories, Inc.
2773 Downhill Drive Steamboat Springs, CO 80437(800) 334-5493
Wright Water Engineers
Project ID:
Sample ID:
181-053.000
WELL TEPEOL
Inorganic Analytical
Results
ACZ Sample ID:
Date Sampled:
Date Received:
Sample Matrix:
L44642-01
05/31118 14:56
06/01/18
Drinking Water
Inorganic Prep
Parameter
EPA Method
Dilution- Ranif `"glal" XQ Units MDL
PQL Date Analyst
Cyanide, total
Phosphorus, total
Total Recoverable
Digestion
Total Recoverable
Digestion
Metals Analysis
M335.4 - Manual Distillation
M365.1 - Auto Ascorbic
Acid Digestion
M200.2 ICP-MS
M200.2 ICP
06/14/18 10:08
06/06/18 14:13 jig/las
06/06/1813:08 mfm
06/19/18 10:19 dcm
Parameter
EPA Method
Dilution Result ---C-Taranhapnits
MDL •V i+L: Date Analyst
Aluminum, total
recoverable
Antimony, total
recoverable
Arsenic, total
recoverable
Barium, total
recoverable
Beryllium, total
recoverable
Cadmium, total
recoverable
Calcium, dissolved
Chromium, dissolved
Copper, total
recoverable
Iron, total recoverable M200.7 ICP
Lead, total recoverable M200.81CP-MS
Magnesium, dissolved M200.7 ICP
M200.7 1CP
Manganese, total
recoverable
Mercury, total
Nickel, total
recoverable
Potassium, dissolved
Selenium, total
recoverable
Silica, dissolved M200.7 ICP
Silver, total recoverable M200.7 ICP
M200.7 ICP
M200.8 ICP-MS
M200.8 ICP-MS
M200.7 ICP
M200.8 ICP-MS
M200.7 ICP
M200.7 ICP
M200.7 ICP
M200.7 ICP
Sodium, dissolved
Thallium, total
recoverable
Uranium, total
recoverable
Zinc, total recoverable
M245.1 CVAA
M200.7 ICP
M200.7 ICP
M200.8 ICP-MS
M200.7 ICP
M200.8 ICP-MS
M200.8 ICP-MS
M200.7 ICP
1
1
u
U
1 0.001 B
0.020
1 U
1
84.3
1
1 0.0005
1 32.5
1
1 2.4
1 0.002
1 27.1
1
1 38.0
1
1 0.0091
1
mg/L
mglL
mg/L
* mg/L
mg/L
0.03
0.2
06/20/18 17:30
aeh
0.0004 0.002 06/14/18 13:08 bsu
0.0005 0.002 06/14/18 13:08 bsu
0.003 0.02 06/20/18 17:30 aeh
0.00005 0.0003 06/14/18 13:08 bsu
U • mg/L 0.005
mg/L
U * mglL
U • mg/L
u
U
mg/L
mglL
mg/L
mg/L
U mg/L
U • mg/L
* mg/L
B mg/L
mg/L
U * mg/L
mg/L
U mg/L
U
mg/L
0.02 06/20/18 17:30 aeh
0.1 0.5 06/19/18 4:50
0.01 0.05 06/19/18 4:50
0.01 0.05 06/20/18 17:30
0.02 0.05
0.0001
0.2 1
0.005 0.03
0.0005
06/20/18 17:30
06/14/18 13:08
06/19/18 4:50
06/20/18 17:30
dcm
dcm
aeh
aeh
bsu
dcm
aeh
0.0002 0.001 06/16/18 11:34 the
0.008 0.04 06/20/18 17:30 aeh
0.2 1 06/19/18 4:50 dcm
0.001 0.005 06/14/18 13:08 bsu
0.2
0.01
0.2 1
0.0001 0.0005
1
0.03
06/19/18 4:50
06/20/18 17:30
06/19/18 4:50
06/14/18 13:08
dcm
aeh
dcm
bsu
0.0001 0.0005 06/14/18 13:08 bsu
mg/L 0.01 0.05
06/20/18 17:30 aeh
REPIN.02.06.05.01
* Please refer to Qualifier Reports for details.
L44642-1806221021
Page 2 of 22
Page 099
ACZ Laboratories, Inc.
2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Wright Water Engineers
Project ID: 181-053.000
Sample ID: WELL TEPEOL
Inorganic Analytical
Results
ACZ Sample ID:
Date Sampled:
Date Received:
Sample Matrix:
L44642-01
05/31/18 14:56
06/01/18
Drinking Water
Wet Chemistry
Parameter
EPA Method
Dilution Result Qual XQ Units MD! PQL Date Analyst
Alkalinity as CaCO3
Bicarbonate as
CaCO3
Carbonate as CaCO3
Hydroxide as CaCO3
Total Alkalinity
Cation -Anion Balance
Cation -Anion Balance
Sum of Anions
Sum of Cations
Chloride
Conductivity @25C
Corrosivity (calc.)
Cyanide, total
Fluoride
Hardness as CaCO3
(dissolved)
Lab Filtration (0.45um
filter)
Lab Filtration (0.45um)
& Acidification
Nitrate as N, dissolved
Nitrate/Nitrite as N,
dissolved
Nitrite as N, dissolved
pH (lab)
pH
pH measured at
Phosphorus, total
Residue, Filterable
(TDS) @180C
Residue, Non -
Filterable (TSS)
@105C
Sulfate
TDS (calculated)
TDS (ratio -
measured/calculated)
Turbidity
SM2320B - Titration
Calculation
SM4500CI-E
SM2510B
SM 2330 - CaCO3 SI
M335.4 - Colorimetric w! distillation
SM4500E-C
SM2340B - Calculation
SOPWC050
M200.7/200.8
Calculation: NO3NO2 minus NO2
M3532 - Automated
Cadmium Reduction
M353.2 - Automated
Cadmium Reduction
SM4500H+ B
M365.1 - Auto Ascorbic
Acid (digest)
SM2540C
SM2540D
SM4500 504-0
Calculation
Calculation
267
U
u
267
mg/L
mg/L
mgiL
mg/L
2 20 06/12/18 0:00 ecc
2 20 06/12/18 0:00
2 20 06/12/18 0:00
2 20 06/12/18 0:00
0.6
8.5 meq/L
8.6 meq/L
1 10.8 * mg/L 0.5 2
1 754 umhos/cm 1 10
1.1 * 5I Unit
0.5 U mg/L 0.003 0.01
1 0.44 mg/ 0.05 0.3
344 mg/L 0.2 5
M180.1 - Nephelometric 1
0.89 mg/L 0.02 0.1
0.89 * mg/L 0.02 0.1
U * mgiL 0.01 0.05
8.2 H units 0.1 0.1
20.2 C 0.1 0.1
U * mg/L 0.02 0.05
492 mg/L 10 20
U * mg/L 5 20
130 * mgiL 10 50
500 mg1L
0.98
U • NTU 0.1 0.5
06/22/18 0:00
06/22/18 0:00
06/22/18 0:00
06/18/18 13:20
06/12/18 17:21
06/22/18 0:00
06/14/18 23:42
06/18/18 18:09
06/22/18 0:00
ecc
ecc
ecc
calc
talc
calc
wtc
ecc
talc
pjb
enb
calc
06/18/1811:25 enb
06/15/1815:30 aeh
06/22/18 0:00 calc
06/01/18 21:48 pjb
06/01/18 21:48 pjb
06/12/18 0:00
06/12/18 0:00
06/12/18 15:40
ecc
ecc
wtc
06/06/1813:48 kja
06/06/1817:28 oah
06/18/18 11:57
06/22/18 0:00
06/22/18 0:00
enb
calc
calc
06/01/1816:32 emk
REPIN.02.06.05.01
Please refer to Qualifier Reports for details.
L44642-1806221021
Page 3 of 22
Page 100
ADZ Laboratories, Inc.
2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
,norganic
eference
Report Header Explanations
Batch
Found
Limit
Lower
MAL
PCN/SCN
PQL
QC
Res
RPD
Upper
Sample
A distinct set of samples analyzed al a specific time
Vatue of the QC Type of interest
Upper limit for RPD, in %.
Lower Recovery Limit, In % (except for LCSS, mg/Kg)
Method Detection Limit. Same as Minimum Reporting Limit unless omitted or equal to the PQL (see comment #5).
Allows for instrument and annual fluctuations.
A number assigned to reagentsistandards to trace to the manufacturer's certificate of analysis
Practical Quantitation Limit. Synonymous with the EPA term "minimum level".
True Value of the Control Sample or the amount added to the Spike
Recovered amount of the true value or spike added, in % (except for LCSS, mg/Kg)
Relative Percent Difference, calculation used for Duplicate QC Types
Upper Recovery Limit, in % (except for LCSS, mg/Kg)
Value of the Sample of interest
QC Sample Types
AS
ASD
CCB
CCV
DUP
ICB
!CV
1CSAB
LCSS
LCSSD
LCSW
Analytical Spike (Post Digestion)
Analytical Spike (Post Digestion) Duplicate
Continuing Calibration Blank
Continuing Calibration Verification standard
Sample Duplicate
Initial Calibration Blank
Initial Calibration Verification standard
Inter -element Correction Standard - A plus B solutions
Laboratory Control Sample - Solt
Laboratory Control Sample - Soil Duplicate
Laboratory Control Sample - Water
LCSWD
LFB
LFM •
LFMD
LRB
MS
MSD
PBS
P8W
PQV
SDL
Laboratory Control Sample - Water Duplicate
Laboratory Fortified Blank
Laboratory Fortified Matrix
Laboratory Fortified Matrix Duplicate
Laboratory Reagent Blank
Matrix Spike
Matrix Spike Duplicate
Prep Blank - Sail
Prep Blank - Water
Practical Quantilatiron Verification standard
Soda! Dilution
pp Sample Type Explanations
Blanks
Control Samples
Duplicates
Spikes/Fortified Matrix
Standard
Verifies that there is no or minimal contamination in the prep method or calibration procedure.
Verifies the accuracy of the method, including the prep procedure.
Verifies the precision of the instrument and/or method.
Determines sample matrix interferences, 11 any.
Verifies the validity of the calibration.
ACZ Qualifiers (Qual),.
8 Analyte concentration detected al a value between MDL and PQL. The associated value is an estimated quantity.
H Analysis exceeded method hold time. pH is a field lest with an immediate hold time.
L Target analyte response was below the laboratory defined negative threshold.
U The material was analyzed for, but was nol detected above the level of the associated value.
The associated value is either the sample quantitntion limit or the sample detection limit,
Method References
(1)
(2)
(3)
(4)
(5)
Comments
(t)
(2)
(3)
(4)
(5)
EPA 60014-83-020. Methods for Chemical Analysis of Water and Wastes, March 1983.
EPA 600/R-93-100. Methods for the Determination of Inorganic Substances in Environmental Samples, August 1993.
EPA 6001R-94-111. Methods for the Determination of Metals in Environmental Samples - Supplement I, May 1994.
EPA SW-846. Test Methods for Evaluating Solid Waste.
Standard Methods for the Examination of Water and Wastewater.
QC results calculated from raw data. Results may vary slightly if the rounded values are used in the calculations.
Soil, Sludge, and Plant matrices for Inorganic analyses are reported on a dry weight basis.
Animal matrices far Inorganic analyses are reported on an "as received" basis.
An asterisk in the "XQ" column indicates there is an extended qualifier and/or certification qualifier
associated with the result.
If the MDL equals the PQL or the MDL column is omitted, the PQL is the reporling limit.
For a complete list of ACZ's Extended Qualifiers, please ctick: http://www.acz.cornipublic/extquallist.pdf
REP001.03.15.02
L44642-1806221021
Page 4 of 22
Page 101
ADZ Laborattries, inc.
2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Wright Water Engineers
InaMnic QC
Summary
ACZ Project ID: L44642
NOTE: If the Rec% column is null, the high/low limits are in the same units as the result. If the Rec% column is not null, then the high/low
limits are in % Rec.
Alkalinity as CaCO3
SM232013 - Titration
ACZ ID
Type Analyzed PCNISCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449279
WG449279P11W1 PBW 06112118 15:56 U mgiL
WG449279LCSW3 LCSW 06/12/18 16:13 WC180531-2 820.0001 815 mg(. 99 90 110
L44675-01DUP DUP 0611211818:08 129 130 mgfL
WG449279LCSW6 LCSW 06112/1819:48 WC180531-2 820.0001 823 mgfL 100 90 110
WG449279PBW2 PBW 06/12/18 19:55 U mg/L -20 20
WG449279LC5W9 LCSW 06112/1823:07 WC188531-2 820.0001 808 11,911- 99 90 110
WG449279PBW3 PBW 06/12/18 23:14 2 m91L -20 20
WG449279LC5W12 LCSW 06/13/182:03 WC180531-2 820.0001 827 mg1L 101 90 110
WG449279PBW4 PBW 06/13/18 2:10 U mg1L -20 20
WG449279LCSW15 LCSW 06/13/18 5:40 WC180531-2 820.0001 834 mg1L 102 90 110
-20 20
1 20
Aluminum, total recoverable
M200.7 ICP
ACZ ID
Type Analyzed PCNISCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449981
WG4499811CV ICV 06/20/18 17:01 11180612-1 2 1.93 mg/L 97 95 105
WG4499811013 ICB 06/20/1817:08 U mg/L -0.09 0.09
WG449789LRB LRB 06/20/18 17:24 U mg/L. -0.066 0.066
WG449789LFB LFB 06/2011817:27 11180608-2 1.0019 1.008 mg8 101 85 115
L44799-01LFM LFM 06/20/18 17:37 11180608-2 1.0019 .16 1.2 mg1L 104 70 130
L44799-01LFMD LFMD 0612011817:40 11180608-2 1.0019 .16 1.195 mgfL 103 70 130 0 20
Antimony, total recoverable
M200.8 ICP-MS
ACZ ID
Type Analyzed PCNISCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449470
WG4494701CV ICV 06/14/18 12:59 M8180423-2 .02 .01853 mglL 93 90 110
WG44947010B ICB 06/14/18 13:01 U mgfL -0.0012 0.0012
WG448814LRB LRB 06/14/18 13:04 U ma -0.00088 0.00088
WG448814LFB LFB 06/14/18 13:05 M0180522-2 .01 .01059 mgAL 106 85 115
L44655-01LFM LFM 06/14/18 13:12 MS180522-2 .01 U .01082 mgiL 108 70 130
L44655-01LFMD LFMD 06/14/1813:13 M8160522-2 ,01 U .01107 mgiL 111 70 130 2 20
Arsenic, total recoverable
M200.8 ICP-MS
o/ ii;
Type Analyzed PCNISCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449470
WG4494701CV ICV 06/14/1812:59 MS180423-2 .05 .04996 mg/L 100 90 110
WG4494701C8 ICB 06/14/18 13:01 U mgfL -0.0015 0.0015
WG448814LRB LRB 06114118 13:04 U mgfL -0.0011 0.0011
WG448814LFB LF6 06/14/18 13:05 M8180522-2 .0501 .04901 mgfL 98 85 115
L44655-01LFM LFM 06/14/18 13:12 M5180522-2 .0501 U .05002 mgiL 100 70 130
L44655-01LFMD LFMD 06/14/18 13:13 M5189522-2 .0501 U .051 m94- 102 70 130 2 20
L44642-1806221021
Page 5 of 22
Page 102
ADZ Laboratories, Inc.
2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Wright Water Engineers
Inorganic QC
Summary
ACZ Project ID: L44642
NOTE: If the Roc% column is null, the high/low limits are in the same units as the result. if the Rec% column is not null, then the high/low
limits are in % Rec.
Barium, total recoverable
M200.7 ICP
ACZ ID
Type Analyzed PCNISCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449981
W G449981 ICV ICV 06/20/18 17:01 11180612-1
WG4499811C8 ICB 06/20/18 17:08
WG449769LR8 LRB 06120118 17:24
W G449789LFB LFB 06/20/18 17:27 11180608-2
L44799-01 LFM LFM 06/20/18 17:37 11160608-2
L44799-01LFMD LFMD 06/20/18 17:40 11180608-2
2 1.9775 mg/1 99 95 105
U mgrL -0.009 0.009
U mg/L -0.0066 0.0066
.5025 .5027 mg1L 100 85 115
.5025 .007 .5068 mgiL 99 70 130
.5025 .007 .5066 mgiL 99 70 130 0 20
Beryllium, total recoverable
M200.8 ICP-MS
ACZ ID
Type Analyzed PCNISCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449470
WG4494701CV ICV 0611411E 12:59 M8180423-2 .05 .048886 mg/L 98 90 110
WG4494701C8 ICB 06/14/18 13:01 U mg/1_ -0.00015 0.00015
WG448814LRB LRB 06/14/18 13:04 U mgiL -0.00011 0.00011
WG448814LFB LFB 06/14/18 13:05 M8180522-2 .05035 .049414 mg/- 98 85 115
L44655-01LFM LFM 06/14/18 13:12 M5180522-2 .05035 U .049949 mg/L 99 70 130
L44655-01LFM0 LFMD 06/14/18 13:13 m61130522-2 .05035 U .050048 mgiL 99 70 130 0 20
Cadmium, total recoverable
M200.7 ICP
ACZ ID
Type Analyzed PCNISCN QC Sample Found Units Roc% Lower Upper RPD Limit Qual
WG449981
WG4499811CV ICV 06/20/18 17:01 11180612-1
W G449981106 ICB 06/20/18 17:08
WG449789LRB LRB 08/20/18 17:24
W G449789LFB LFB 06/20/18 17:27 11180608-2
L44799-01LFM LFM 06/20/18 17:37 11180608-2
L44799-01LFMD LFMD 06/20/18 17:40 11180608-2
2 2.0013 mg1L 100 95 105
U mg/L -0.015 0.015
U mg/L -0.011 0.011
.4975 .5002 mg11- 101 85 115
.4975 U .5008 mgiL 101 70 130
.4975 U .4993 mg11- 100 70 130 0 20
Calcium, dissolved
M200.7 ICP
ACZ ID
Type Analyzed PCNISCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449759
WG4497591CV ICV 06/19/184:29 11180612-1 100 99.55 mgfL 100 95 105
WG4497591CB ICB 06/19/18 4:35 U mglt. -0.3 0.3
WG449759LFB LFB 06/19/18 4:47 11180608-2 68,22088 68.74 mg/L 101 85 115
L44826-01AS AS 06/19/18 5:15 11180608-2 68.22088 100 164.6 m91L 95 85 115
L44826-01ASD ASD 06/19/18 5:24 11180608-2 68.22088 100 165.4 mg/L 96 85 115 0 20
Chloride
SM4500CI-E
ACZ ID
Type Analyzed PCNISCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449717
WG4497171CB ICB 06/18/18 12:18 U mg/L -1.5 1.5
WG4497171CV ICV 06/18/18 12:18 W1180530-1 54.89 58.22 mg/L 106 90 110
WG449717LF01 LFB 06/18/1813:18 W1171229-5 30.03 32.97 mgiL 110 90 110
144622-03DUP DUP 06/18/18 13:20 22 21.58 mg/L
144642-01AS AS 06/18/18 13:20 W1171229-5 30.03 10.8 43.16 m9&L 108 90 110
WG449717LFB2 LFB 06/18/18 13:35 W1171229-5 30.03 31.51 mgiL 105 90 110
2 20
L44642-1806221021
Page 6 of 22
Page 103
ACZ Laboratories, Inc.
2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Wright Water Engineers
Inorganic QC
Summary
ACZ Project ID: L44642
NOTE: if the Rec% column is null, the high/low limits are in the same units as the result. !f the Rec% column is not null, then the high/low
limits are in % Rec.
Chromium, dissolved
M200.7 ICP
ACZ ID
Type Analyzed POI/SCR QC Sample Found Units Rec% Lower Upper RPD Limit Qua!
WG449759
W G4497591CV ICV 06/19/18 4:29 11180612-1
WG4497591C9 ICB 06/19/18 4:35
W G449759LFB LFB 06/19/18 4:47 11180608-2
L44826-01AS AS 06/19/18 5:15 11180608-2
L44626-01ASD ASD 06/19/18 5:24 11180608-2
2 1.968 mglL 98 95 105
U mg/L -0.03 0.03
.5 .519 mg/L 104 85 115
.5 U .515 MO- 103 85 115
.5 U .525 m9+1- 105 85 115 2 20
Conductivity @25C
SM2510B
ACZ ID
Type Analyzed PCN/SCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449279
WG449279LCSW2 LCSW 06/12/18 16:01 PC1,155011
L44675-01DUP DUP 06/12/1818:08
WG449279LCSW5 LCSW 00/1211819:36 PCN55811
WG449279LCSW8 LCSW 06/12/1822:56 PCN55811
WG449279LCSW11 LCSW 06/13/18 1:51 PCN55811
WG449279LCSW14 LCSW 06/13/185:28 PCN55811
1410 1460 umhoslcm 104 90 110
263 260 umhoslcm 1 20
1410 1450 umhoslcm 103 90 110
1410 1450 umhoslcm 103 90 110
1410 1440 umhoslcm 102 90 110
1410 1430 umhoslcm 101 90 110
Copper, total recoverable
M200.7 ICP
ACZ ID
Type Analyzed PCN/SCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449981
WG4499811CV ICV 06/20/18 17:01
WG4499811CB ICB 06/20/18 17:08
WG449789LRB LRB 06/20/18 17:24
WG449789LFB LFB 06/20/18 17:27
L44799-01LFM LFM 06/20/18 17:37
L44799-01 LFMD LFMD 06/20/18 17:40
11188612-1 2 1.958 mg/L 98 95 105
U mg/L -0.03 0.03
U mg/L -0.022 0.022
11180608-2 .4975 .501 mg/L 101 85 115
11180808-2 .4975 U .499 mgl1- 100 70 130
11180608-2 .4975 U .496 mg/L 100 70 130 1 20
Cyanide, total
M335.4 - Colorimetrlc w/ distillation
ACZ ID
Type Analyzed PCN/SCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449533
WG4495331CV ICV 06/14/1822:06 W1180613-2 .3003
WG4495331CB ICB 06/14118 22:07
W G449535
.2821 mg/L 94 90 110
U mg/L
-0.003 0.003
WG449446LRB LRB 06/44/18 23:37 U mg(L -0.003 0.003
WG449446LFB LFB 06/14/18 23:37 W118060816-2 .2 .1824 mg(L 91 90 110
L44569-10DUP DUP 06/14/18 23:39 U U raga_ 0 20 RA
L44569-11LFM LFM 06/14/1823:41 W138060618-2 .2 U .1892 mg/L 95 90 110
Fluoride
SM4500E-C
ACZ ID j Type Analyzed PCNISCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449719
WG4497191CV ICV 06/18/18 17:15 WC180611-13 1.996 1.995 mg1L 100 95 105
WG4497191C8 ICB 06/18/18 17:21 U mg1L -0.15 0.15
WG449719LFB1 LFB 06/18/18 17:30 WC180508-10 5.015 5 mg/L 100 90 110
L42793-17AS AS 06/18/18 17:46 WC180508-10 5.015 .31 5.178 Mil- 97 90 110
L42793-17ASD ASD 06/18118 17:54 WC1B05118-10 5.015 .31 5.1 mg!1 96 90 110 2 20
WG449719LFB2 LFB 06/18/18 20:39 WC180508-10 5.015 4.953 mg/L 99 90 110
L44642-1806221021
Page 7 of 22
Page 104
ACZ Laboratories, Inc.
2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Wright Water Engineers
Inorganic QC
Summary
ACZ Project ID: L44642
NOTE:1f the Rec% column is Trull, the high/low limits are in the same units as the result. if the Rec% column is not null, then the high/low
limits are in % Rec.
Iron, total recoverable
M200.7 ICP
ACZ ID
Type Analyzed PCN/SCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449981
WG4499811CV ICV 06/20/18 17:01 11180812-1 2 1.937 mg/L 97 95 105
WG4499811CB ECB 06/20/18 17:08 U mgr.. -0.06 0.06
WG449789LRB LRB 06/20/18 17:24 U mg/L -0.044 0.044
WG449789LFB LFB 0612011817:27 61180608-2 1.0011 1.008 man- 101 85 115
L44799-01LFM LFM 06/20/18 17:37 11180608-2 1,0011 .15 1.166 mgfL 101 70 130
L44799-01LFMD LFMD 06/20/18 17:40 11180608-2 1.0011 .15 1.16 mg/L 101 70 130 1 20
Lead, total recoverable
M200.8 ICP-MS
ACZ ID
Type Analyzed PCNISCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449470
WG4494701CV ICV 06114/18 12:59 M6188423-2 .05 .05177 mgfL 104 90 110
WG4494701CB ICB 06/14/18 13:01 U rng/L -0.0003 0.0003
WG448814LRB LRB 06/14118 13:04 U mg/L -0.00022 0.00022
WG448814LFB LFB 06/14/18 13:05 MS180522-2 .0496 .09922 mgfi 99 85 115
L44655-01LFM LFM 06/14/18 13:12 MS180522-2 .0496 .0018 .05104 ma 99 70 130
L44655-01LFMD LFMD 06/14/18 13:13 M8180522-2 .0496 .0018 .05107 mg/L 99 70 130 0 20
Magnesium, dissolved
M200.7 ICP
ACZ ID
Type Analyzed PCN/SCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449759
WG4497591CV ICV 06/19/184:29 11180612-1 100 99.45 mgn- 99 95 105
WG4497591CB ICB 06/19/184:35 U mgrL -0.6 0.6
WG449759LFB LFB 06/19/184:47 11180608-2 50.05667 48.81 mgfL 98 85 115
L44826-01AS AS 06/19/18 5:15 11180608-2 50.05667 7.3 56.86 mg1L 99 85 115
L44826-01ASD ASD 06/19/185:24 11180608-2 50.05667 7.3 56.85 mall 99 85 115 0 20
Manganese, total recoverable
M200,7 ICP
ACZ ID
Type Analyzed PCNISCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449981
WG4499811CV ICV 06/20/18 17:01 11180612-1 2 1.9818 mgfL 99 95 105
WG4499811CB ICB 06120/18 17:08 U mg/L -0.015 0.015
WG449789LRB LRB 06/20/18 17;24 U mg/L -0.011 0.011
WG449789LFB LFB 06/20118 17:27 11180606-2 .5005 .508 mg/L 101 85 115
144799-01LFM LFM 06/20/18 17:37 11180808-2 .5005 U .5119 mgfL 102 70 130
144799-01LFMD LFMD 0812011817:90 11160608-2 .5005 U .5107 m811. 102 70 130 0 20
Mercury, total
M245.1 CVAA
ACZ ID
Type Analyzed PCN/SCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449591
WG4495911CV1 ICV 06/16/1810:54 HG180607a .004995
WG4495911C0 ICB 06/16/18 10:57
WG449593
.00488 mg/L 98 95 105
U mg/L -0.0002 0.0002
WG449593LRB LRB 06/16/18 11:32 U mg/L -0.00044 0.00044
WG449593LFB LFB 06/16/1811:33 HG180530-3 .002002 .00184 man- 92 85 115
L44816-01LFM LFM 06/16(18 11:39 HG1110530-3 .002002 U .0019 mg/L 95 85 115
L44616-01LFM❑ LFMD 06/16/18 11:40 11G180530-3 .002002 U .00187 mgfL 93 85 115 2 20
IL44642-1806221021
Page 8 of 22
Page 105
ACZLaboratories, inc.
2773 Downhill Drive Steamboat Springs, CC 80487 (800) 334-5493
Wright Water Engineers
Inorganic QC
Summary
ACZ Project ID: L44642
NOTE: If the Rec% column is null, the high/low limits are in the same units as the result. If the Rec% column is not null, then the high/low
limits are in % Rec.
Nickel, total recoverable
M200.7 ICP
ACZ ID
Type Analyzed
PC141SCN QC Sample Found Units Roc% Lower Upper RPD Limit Dual
WG449981
WG4499811CV ICV 06/20/18 17:01
W64499811CB ICB 06/20/18 17:08
WG449789LRB LRB 06/20/18 17:24
WG449789LFB LFB 06/20118 17:27
L44799-01LFM LFM 06/20/16 17:37
L44799-01LFMD LFMD 06/20/18 17:40
11180612-1
11180606-2
11180608-2
11180608-2
2.004
.5015
.5015
.5015
U
u
1.9792
u
U
.51
.5151
.5095
mg/L
mg/L
mgiL
mgiL
mgiL
mgiL
99 95 105
-0.024 0.024
-0.0176 0.0176
102 85 115
103 70 130
102 70 130 1 20
Nitrate/Nitrite as N, dissolved
M353.2 - Automated Cadmium Reduction
ACZ ID
Typo Analyzed
PCN/SCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG448576
WG4485761CV ICV 06/01/18 20:47 W1180301-7 2.416
WG4485761CB ICB 06/01/1820:49
WG448576LFB1 LFB 06/01/18 20:54 W1180103-12 2
WG448576LFB2 LFB 06/01/1821:34 W1180103-12 2
L44614-02AS AS 06/01/1821:41 W1180163-12 2
L44622-01DUP DUP 06/01/1821:43
U
U
2.415
U
2.032
2.045
1.899
U
rng/L
mg1L
mgiL
mg/L
mg1L
mg1L
100 90
-0.02
102 90
102 90
95 90
110
0.02
110
110
110
0 20 ftA
Nitrite as N, dissolved
M353..2 - Automated Cadmium Reduction
ACZ ID
Type Analyzed
PCN/SCN QC Sample Found Units Rec% Lower p ,D Limit Qual
WG448576
W G4485761CV
W G4485761CB
WG448576LFB1
WG448576LFB2
L44614-02AS
L44622-01 DUP
ICV
ICB
LFB
LFB
AS
DUP
06/01/18 20:47
06/01/18 20:49
06/01/18 20:54
06/01/18 21:34
06/01/18 21:41
06/01/18 21:43
WI180301-7 .609 .621 mgiL
U mgfL
W 1180103-12 1 1.012 mgiL
W1180103-12 1 1.032 mgiL
W1180103-12 1 U .59 mgfL
U U mg/L
102 90
-0.01
101 90
103 90
59 90
110
0.01
110
110
110
M2
0 20 RA
pH (lab)
SM4500H+ B
r:(-FIL)
Type Analyzed
PCNISCN QC
Sample.
I;til LUittt3
Upper
Qual.
WG449279
WG449279LCSW 1
L44675-01 DUP
WG449279LCSW4
WG449279LCSW 7
LCSW
DUP
LCSW
LCSW
WG449279LCSW10 LCSW
WG449279LCSW13 LCSW
06/12/18 15:59
06/12/1818:08
06/12/18 19:34
06/12/18 22:54
06/13/18 1:49
06/13/18 5:26
PCN54162
PCN54162
PCN54162
PCN54162
PCN54162
6.01
6.01
6.01
6.01
6.01
8.3
Phosphorus, total
6.1
8.3
6.1
6
6
6
M365.1 - Auto Ascorbic Acid (digest)
units
units
units
units
units
units
101 5.9 6.1
101
100
100
100
5.9
5.9
5.9
5.9
6.1
6.1
6.1
6.1
0 20
ACZ ID Type Analyzed
PCN/SCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
W G449264
WG4492641CV ICV 06/12/18 13:28 W1180601-8 .65228
WG4492641C8 ICB 06/12/1813:30
WG449274
WG448844LRB LRB 06/12/18 15:25
WG448844LFB LFB 06/12/1815:26
L44605-02LFM LFM 06/12/18 15:28
L44613-01DUP DUP 06/12/18 15:30
W1180605-7 .5
W1180605-7 .5
.651 mg/L
U mgiL
U
.492
U .505
.43 .374
mgiL
mgiL
mgfL
rng/L
100 90 110
-0.02 0.02
-0.02
98 90
101 90
0.02
110
110
14 20
L44642-1806221021
Page 9 of 22
Page 106
ACZ Laboratories, inc.
2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Wright Water Engineers
Inorganic QC
Summary
ACZ Project ID: L44642
NOTE: If the Rec% column is null, the high/low limits are in the same units as the result. if the Rec% column is not null, then the high/low
limits are in % Rec.
Potassium, dissolved
M200.7 ICP
ACZ ID
Type Analyzed PCN/SCN QC Sample Found Units Rec% Lower Upper RPD Limit Qua'
WG449759
WG44975910V ICV 06/19/18 429 11180612-1 20 19.88 mg/L 99 95 105
WG4497591CB ICB 06/19/18 4:35 U mgfL -0.6 0.6
W0449759LF6 LFB 06/19/18 4:47 11100608-2 99.72934 100 m28- 100 85 115
L44826-01AS AS 06/19/18 5:15 11180608-2 99.72934 6.3 109.4 m911- 103 85 115
L44826-01ASD ASD 06/19/18 5:24 11180608-2 99.72934 6.3 109.7 mgn 104 85 115 0 20
Residue, Filterable (TDS) @180C
SM2540C
ACZ ID
Typ Analyzed PCNISCN QC Sample Found Uni s )Rec%
Lower Uppp---. . ICI€il(?' Cclxll
WG448864
WG448864PBW PBW 06/06/18 13:45 U mg/L
WG448864LCSW LCSW 06/06/18 13:46 PCN55373 260 262 mg/ 101 80 120
L44675-01DUP DUP 06/06/18 14:01 194 196 mg/L
-20 20
1 10
Residue, Non -Filterable (TSS) @105C
ACZ 1D
SM2540❑
Type Analyzed PCN/SCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
PCN55373 160
W6446878
WG448878PBW PBW 06/06/18 17:00
WG448878LCSW LCSW 06106/1817:02
L44642-01DUP DUP 06/06/18 17:31
V mg/L
157 mg/L 98 80 120
u u mg/L
-15 15
0 10 RA
Selenium, total recoverable
M200.8 ICP-MS
ACZ ID
Type Analyzed PCN/SCN QC Sample Found Units Rec% Lower Upper RPD Limit pilaf
WG449470
WG4494701CV ICV 06/14/18 12:59 M6180423-2 .05 .0545 mg/L 109 90 110
WG4494701C0 ICB 0611411813:01 U mg/L -0.003 0.003
WG448814LR8 LRB 06/1411813:04 U mg/L -0.0022 0.0022
WG448814LF8 LFB 06/14/18 13:05 M8186522-2 .05005 .0489 mgIL 98 85 115
L44655-01LFM LFM 06/14/18 13:12 Ms180522-2 .05005 U .0492 m911- 98 70 130
L44655-01LFMD LFMD 06/14/18 13:13 MS180522-2 .05005 U .0504 mg11- 101 70 130 2 20
Silica, dissolved
M200.7 ICP
ACZ ID
Type Analyzed PCN/SCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449759
WG4497591CV ICV 06/19/184:29 11180612-1 42.8 41.44 mg/L 97 95 105
WG4497591CB ICS 06/19/184:35 U mg/L -0.6 0.6
WG449759LF6 LFB 06/19/18 4:47 11180608-2 21.415 22.89 mg/L 107 85 115
L44826-01AS AS 06/19/185:15 111808e8-2 21.415 52.5 72.86 m9/1- 95 85 115
L44826-01ASD ASD 06/191185:24 11180608-2 21A15 52.5 72.46 mgfL 93 85 115 1 20
L44642-1806221021
Page 10 of 22
Page 107
ADZ Laboratories, Inc.
2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Wright Water Engineers
r Inorganic QC
Summary
ACZ Project ID: L44642
NOTE: If the Rec% column is null, the high/low limits are in the same units as the result. If the Rec% column is not null, then the high/low
limits are in % Rec.
Silver, total recoverable M200.7 ICP
ACZ ID
Type Analyzed PCNISCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449981
W G449981 ICV ICV 06/20/18 17:01 11180612-1 1.001
WG449981106 ICB 06120/18 17:08
WG449789LRB LRB 06/20/18 17:24
WG449789LFB LFB 06/20/18 17:27 11180008-2 ,5
L44799-01 LFM LFM 06/20/18 17:37 11180608-2 .5
L44799-01LFMD LFMD 06/20/18 17:40 11180608-2 .5
1.005 nit. 100 95 105
U mgrL -0.03 0.03
U mgrL -0.022 0.022
.497 mg/L 99 85 115
U .493 mg/L 99 70 130
U .493 mg/L 99 70 130 0 20
Sodlum, dissolved
M200.7 ICP
ACZ ID Type Analyzed PCNISCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449759
WG44975910V ICV 06/19/18 4:29 11180612-1 100 100.44 mgfl- 100 95 105
WG4497591CB ICB 06/19/18 4:35 U mg1L -0.6 0.6
WG449759LFB LFB 06/19/18 4:47 i1180608-2 100.6711 101.8 mg/L 101 85 115
L44626-01AS AS 06/19/185:15 E1180608-2 100.6711 22.2 125.2 m91L 102 85 115
L44826-01ASD ASD 06/19/18 5:24 11180608-2 100,6711 22.2 125.4 mg1L 103 85 115 0 20
Sulfate
SM4500 504-❑
ACZ ID
Type Analyzed PCNISCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449698
WG449690PBW PBW 06/1811811:50 U mg/L
WG449698LCSW LCSW 06/18/18 11:53 WC170902-4 100 102 mg/L 102 80 120
L44860-05DUP DUP 0611811812:32 290 281 mg/L
Thallium, total recoverable
M200.8 ICP-MS
-30 30
3 20
ACZ ID
Type Analyzed PCNISCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449470
WG4494701CV ICV 06/14/18 12:59 M3180423-2 .05 .0528 mg/L 106 90 110
WG4494701C8 ICB 06/14/18 13:01 U mg/L -0.0003 0.0003
WG448814LRB LRB D6/14/18 13:04 U mg/L -0.00022 0.00022
WG448814LFB LFB 0611471813:05 MS180522-2 .0501 .0504 mg/L 101 85 115
L44655-01LFM LFM 06/14/18 13:12 M8180522-2 .0501 U .05032 mg/L 100 70 130
144655-01LFMD LFMD 061141813:13 M0180522-2 .050i U .05054 mg/L 101 70 130 0 20
Turbidity
M180.1 - Nephelometric
ACZ ID
Type Analyzed PCNISCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG448570
WG4485701CV ICV 06/01/18 16:21 PCN54160
W044857010V1 ICV 06/01/18 16:23 PCN541e0
WG448570ICB ICB 06/01/1818:24
L44642-01DUP ❑UP 06/01/18 16:33
205 213 NTU 104 90 110
205 213 NTU 104 90 110
U NTU -0.3 0.3
U U NTU 0 20 RA
L44642-1806221021
Page 11 of 22
Page 108
ACZ Laboratories, Dnc.
2773 Downhill drive Steamboat Springs, CO 80487 (800) 334-5493
Wright Water Engineers
Inorganic QC
Summary
ACZ Project ID: L44642
NOTE if the Rec% column is null, the high/low limits am in the same units as the result. If the Rec% column is not null, then the high/low
limits are in % Rec.
Uranium, total recoverable
M200.8 ICP-MS
ACZ ID
Type Analyzed PCN(SCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449470
WG4494701CV ICV 06114/18 12:59 M3180423-2
WG4494701C8 ICB 06/14/18 13:01
WG448814LRB LRB 06/14/18 13:04
WG448814LFB LFB 06/14/18 13:05 M6180522-2
L44655-01LFM LFM 06/14/19 13:12 MS180522-2
L44655-01LFMD LFMD 06/14/18 13:13 M5180522-2
.05 .05049 m011- 101 90 110
U mg1L -0.0003 0.0003
U mg./ -0.00022 0.00022
.05 .04982 mgrL 100 85 115
.05 .0017 .05247 mg11 102 70 130
.05 .0017 .05293 mglL 102 70 130 1 20
Zinc, total recoverable
M200.7 ICP
ACZ ID Type Analyzed PCNISCN QC Sample Found Units Rec% Lower Upper RPD Limit Qual
WG449981
WG4499811CV ICV 06/20/18 17:01 11180612-1 2 2.015 mgrL 101 95 165
WG4499811CB ICB 06/20/18 17:08 U mg/L -0.03 0.03
WG449789LRB LRB 06/20/18 17:24 U mgrL -0.022 0.022
WG449789LFB LFB 06/20/18 17:27 11180608-2 4942 .524 mg/L 106 85 115
L44799-01LFM LFM 06/20/18 17:37 11180808-2 .4942 U .522 mglL 106 70 130
L44799-01LFMD LFM 06/20/18 17:40 11180608-2 .4942 U .522 mg/L 106 70 130 0 20
L44642-1806221021 Page 12 of 22
Page 109
ADZ Laboratories, Inc.
2773 Downhill Drive Steamboat Springs, CO 80487 (800) 339-5493
Wright Water Engineers
ACZ Project ID: L44642
ACZ ID WORKNUM PARAMETER
METHOD
QUAL DESCRIPTION
L44642-01 RG639152 Corrosivity (calc.)
WG449535 Cyanide, total
WG448576 Nitrate/Nitrite as N, dissolved
Nitrite as N, dissolved
SM 2330 - CaCO3 SI
M335.4 - Calorimetric wl
distillation
M353.2 - Automated Cadmium
Reduction
M353.2 - Automated Cadmium
Reduction
M353.2 - Automated Cadmium
Reduction
M353.2 - Automated Cadmium
Reduction
M353.2 - Automated Cadmium
Reduction
WG448B78 Residue, Non -Filterable (TSS) [a]1056 5M2540D
WG448570 Turbidity
M180.1 - Nephelametric
ZZ
RA
RA
zu
M2
RA
zu
RA
RA
Laboratory measured pH and temperature were used in this
calculation. Sampler did not report either field pH, field
temperature, or both.
Relative Percent Difference (RPD) was not used for data
validation because the concentration of the duplicated
sample Is too tow for accurate evaluation (< 10x MDL),
Relative Percent Difference (RPD) was not used for data
validation because the concentration of the duplicated
sample is too low for accurate evaluation (< 10x MDL).
Analysis date/time preceeds filter dateltime. A portion of
sample was filtered and analyzed prior to the creation of a
Filter workgroup.
Matrix spike recovery was low, the recovery of the
associated control sample (LCS or LFB) was acceptable.
Relative Percent Difference (RPD) was not used for data
validation because the concentration of the duplicated
sample is too low for accurate evaluation (< 10x MDL).
Analysis dateltime preceeds filter dateltime. A portion of
sample was filtered and analyzed prior to the creation of a
Filter workgroup.
Relative Percent Difference (RPD) was not used for data
validation because the concentration of the duplicated
sample is too low for accurate evaluation (< 10x MDL),
Relative Percent Difference (RPD) was not used for data
validation because the concentration of the duplicated
sample is too low for accurate evaluation (< 10x MDL).
REPAD.15.06.05.01
L44642-1806221021 Page 13 of 22
Page 110
ADZ Laboratories, Inc.
2773 Downhill Drive Steamboat Springs, GO 80487 (800) 334-5493
Wright Water Engineers
Project ID:
Sample ID:
Locator:
181-053.000
WELL TEPEOL
dioChemistry
nalytical Results
ACZ Sample ID:
Date Sampled:
Date Received:
Sample Matrix:
L44642-01
05/31/18 14:56
06/01/18
Drinking Water
Gross Alpha & Beta
M900.0
Parameter Measure Date
Alpha
Beta
06/16/18 0:07
06116118 0:07
Prep Date
Result Error(+t-) LLD
7.3
3.3
3.3
2.4
3.4 3.4
Prep Method:
Units XQ.
pCi/L
pCi/L
slmljlg
stm/jlg
REPRC.02.06.05.01
Please refer to Qualifier Reports for details.
L44642-1806221021 Page 14 of 22
Page 111
ADZ Laboratories, Inc.
2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Radiochemistry
Reference
Report Header Explanations
Batch A distinct set of samples analyzed at a specific time
Error(+/-) Calculated sample specific uncertainly
Found Value of the QC Type of interest
Limit Upper limit for RPD, in %.
LCL Lower Control Limit, in V. (except for LCSS, mg/Kg)
LLD Calculated sample specific Lower Limit of Detection
PCN/SCN A number assigned to reagents/standards to trace to the manufacturer's certificate of analysis
PQL Practical Quantitation Limit
QC True Value of the Control Sample or the amount added to the Spike
Rec Amount of the true value or spike added recovered, in % (except for LCSS, mg/Kg)
RER Relative Error Ratio, calculation used for Dup. QC taking into account the error factor.
RPD Relative Percent Difference, calculation used for Duplicate QC Types
UCL Upper Control Limit, in % (except for LOSS, mg/Kg)
Sample Value of the Sample of interest
QC Sample Types
DUP
LCSS
LCSW
Sample Duplicate
Laboratory Control Sample - Soil
Laboratory Control Sample - Water
MS/MSD
PBS
PBW
Matrix Spike/Matrix Spike Duplicate
Prep Blank - Soil
Prep Blank - Water
QC Sample Type Explanations
Blanks
Control Samples
Duplicates
Matrix Spikes
Verifies that there Is no or minimal contamination in the prep method procedure.
Verifies the accuracy of the method, Including the prep procedure.
Verifies the precision of the instrument and/or method.
Determines sample matrix interferences, if any.
ACZ Qualifiers (Qual)
H Analysis exceeded method hold time.
Method Prefix Reference
M
SM
D
RP
ESM
Comments
(1)
(2)
(3)
(4)
EPA methodology, Including those under SDWA, CWA, and RCRA
Standard Methods for the Examination of Water and Wastewater.
ASTM
DOE
DOE/ESM
Solid matrices are reported on a dry weight basis.
Preparation method: "Method" indicates preparation defined In analytical method.
QC results calculated from raw data. Results may vary slightly if the rounded values are used in the calculations.
An asterisk in the "XQ" column indicates there is an extended qualifier and/or certification
qualifier associated with the result.
For a complete list of ACZ's Extended Qualifiers, please click: http://www.acz.Coro/public/exkluallist.pdf
REP003.09.12.01
L44642-1806221021
Page 15 of 22
Page 112
ACZ Laboratories, Inc,
2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Wright Water Engineers
Radiochemistry QC
Summary
ACZ Project ID: L44642
Alpha
NOTE: if the Rec% column is null, the high/low limits are in the same units as the result. If the Rec% column is not null, then the high/low limits are in % Rec.
M900.0
Units: pCi/L
ACZ ID Type Analyzed PCN/SCN QC Sample Milk,LD Found Error LLD Rec% Lower Upper RPDIRER Limit Qual
WG449738
WG449728PBW PBW 06/16/18
WG449728LCSW LCSW 06/16/18 PCN55778
L44642-01DUP DUP-RPD 06/16/18
L44642-01DUP DUP-RER 06/16/18
L44703-02DUP DUP-RPD 06/16/18
L44736-05MS MS 06/16/18 PCN55778
.06 0.83 1.1
100 100 8.7 1.7 100 67 144
7.3 3.3 2.4 9.6 3.6 2.2
7.3 3.3 2.4 9.6 3.6 2.2
4.8 3 2.5 4.8 3 2.5
100 2.9 2.3 5.7 85 8.9 4.6 82 67 144
2.2
27 20 RG
0.47 2
0 20
Beta
M900.0
Units: pCi1L
ACZ ID Type Analyzed PCN/SCN QC SampI er LLD Found Error LLD Rec% Lower Upper RPDIRER Limit Qual
WG449738
WG449728PBW PBW 06/15/18 2
WG449726L05W LCSW 06/16/18 RC180320-10 100 92
L44642-01DUP DUP-RPD 06/15/18 3.3 3.4 3.4 8.5
L44642-01DUP DUP-RER 06/16/18 3.3 3.4 3.4 8.5
L44703-02DUP DUP-RPD 06/15/18 3.1 3 3 3.6
L44736-07MS MS 0e/16/18 RC180320-10 100 3.9 3 7.3 100
2 1,9
6.2 2.6 92 82 122
3.5 3.1
3.5 3.1
3.4 3.4
7 7.8 96 82 122
3.8
88 20 RG
1.07 2
15 20
L44642-1806221021
Page 16 of 22
ADZ Laboratories, Inc.
2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Wright Water Engineers
RadChem Extended
Qual%Report
ACZ Project ID: L44642
ACZ ID WORKNUM PARAMETER
METHOD QUAL DESCRIPTION
L44642.01 NG449738 Alpha
Beta
M900.0 RG Sample concentration is less than 5x LLD; RPD was not
used for data validation. Replicate Error Ratio (RER) is
less than 2. Precision judged to be in control.
M900.0 RG Sample concentration is less than 5x LLD; RPD was not
used for data validation. Replicate Error Ratio (RER) is
less than 2. Precision judged to be in control.
REPAD.15.06.05.01
L44642-1806221021 Page 17 of 22
Page 114
ADZ Laboratories, Inc.
2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Wright Water Engineers
Certification
Qualifiers
ACZ Project ID: L44642
Metals Analysis
The following parameters are not offered for certification or are not covered by NELAC certificate f#ACZ.
Barium, total recoverable
Cadmium, total recoverable
Chromium, dissolved
Copper, total recoverable
Nicke€, total recoverable
Potassium, dissolved
Silver, total recoverable
Wet Chemistry
M200.7 ICP
M200.7 ICP
M200.7 ICP
M200.7 ICP
M200.7 ICP
M200.7 ICP
M200.7 ICP
Ite`falloiwing parameters are not offered for certification or are not covered by NELAC clagatejjACZ.
Chloride
Phosphorus, total
Residue, Non -Filterable (TSS) @105C
Sulfate
SM4500CI-E
M365.1 - Auto Ascorbic Acid (digest)
SM25400
SM4500 504-D
REPAD.05.06.05.01
L44642-1806221021 Page 18 of 22
Page 115
ACZ Laboratories, Inc.
2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Wright Water Engineers
181-053.000
Sample
Receipt
ACZ Project ID: L44642
Date Received: 06101 /2018 11:05
Received By:
Date Printed:
6/4/2018
Receipt Verification.
1) Is a foreign soil permit included for applicable samples?
2) Is the Chain of Custody form or other directive shipping papers present?
3) Does this project require special handling procedures such as CLP protocol?
4) Are any samples NRC licensable material?
5) If samples are received past hold time, proceed with requested short hold time analyses?
6) Is the Chain of Custody form complete and accurate?
7) Were any changes made to the Chain of Custody form prior to ACZ receiving the samples?
YES
NO
NA
X
LX
X
Samples/Containers
8) Are all containers intact and with no leaks?
9) Are ail labels on containers and are they intact and legible?
10) Do the sample labels and Chain of Custody form match for Sample ID, Date, and Time?
11) For preserved bottle types, was the pH checked and within limits?
12) Is there sufficient sample volume to perform all requested work?
13) Is the custody seal intact on all containers?
14) Are samples that require zero headspace acceptable?
15) Are all sample containers appropriate for analytical requirements?
16) Is there an Hg-1631 trip blank present?
17) Is there a VOA trip blank present?
18) Were all samples received within hold time?
1
YES
X
NO
X
L
X
NA
x 111iitl
NA indicates Not Applicable
Chain of Custody RJR: trd111Marks
Client Contact Remarks
Shipping Containers
Cooler Id Temp CC) Temp
Criteria CC)
3963
1.4 <=6.0
Rad(pR/Hr) Custody Seal
Intact?
15
Yes
Was ice present in the shipment container(s)?
Yes - Wet ice was present in the shipment container (s).
Client must contact an ACZ Project Manager if analysis should not proceed for samples received
outside of their thermal preservation acceptance criteria.
REPAD LPII 2012-03
L44642-1806221021
Page 19 of 22
Page 116
ADZ Laboratories, Inc.
2773 Downhill Drive Steamboat Springs, CO 80487 (800) 334-5493
Wright Water Engineers
181-053.000
Sample
Receipt
ACZ Project ID: L44642
Date Received: 06/01/2018 11:05
Received By:
Date Printed: 6/4/2018
1 The preservation of the following bottle types is not checked at sample receipt: Orange (oil and
grease), Purple (total cyanide), Pink (dissolved cyanide), Brown (arsenic speciation), Sterile (fecal
coliform), EDTA (sulfite), HCI preserved vial (organics), Na2S2O3 preserved vial (organics), and
HG-1631 (total/dissolved mercury by method 1631).
REPAD LPII 2012-03
L44642-1806221021 Page 20 of 22
Page 117
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Page 21 of 22
Page 118
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L44642-1806221021
Page 22 of 22
Page 119